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yarga [219]
3 years ago
15

A total of 663 cal 663 cal of heat is added to 5.00 g 5.00 g of ice at − 20.0 °C . −20.0 °C. What is the final temperature of th

e water?
Chemistry
1 answer:
Serjik [45]3 years ago
4 0

Answer:

Final Temperature = 305.9 K or 32.9°C

Explanation:

Information given;

Mass (m) = 5g

Amount of Heat (H) = 663 calories

Initial Temperature = -20°C + 273 = 253K (Converting to Kelvin Temperature)

Final Temperature?

Specific Heat capacity of Water (c) =?

One might probably rush to use H = m * c * (T2-T1) to calculate the fianl temperature. That would have been wrong because Ice would melt when heat is being applied to it. And using that formular directly would lead to not considering the amount of heat required to melt it.

First let us check the amount of heat required to raise the temperature of the ice to 0°C

In this case now; Final temperature = 0°C + 273 = 273 K (Converting to Kelvin)

H = m * c * (T2-T1)

H = 5 * 1 * (273 - 253)

H = 5 * 1 * 20 = 100 cal

This shows the heat supplied is enough (663 cal is more than 100 cal) to bring the ice to its melting point.

Let's see if it would be sufficient to melt it.

Amount of Heat required to Melt ice;

H = mL;

where L = heat of fusion = 79.7 cal/g

H = 5 * 79.7 = 398.5 cal

Again, the heat is sufficient to melt it; the remaining heat would be used in raising the temperature of the liquid water.

In this case, initial temperature = 0°C + 273 = 273 K (Converting to Kelvin)

Amount of Heat left = 663 - 398.5 - 100 = 164.5 cal

Final temperature is given as;

H = m * c * (T2-T1)

164.5 = 5 * 1 * (T2 - 273)

T2 - 273 = 164.5 / 5

T2 = 273 + 32.9 = 305.9 K

Final Temperature = 305.9 K or 32.9°C

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A mixture of 75 mole% methane and 25 mole% hydrogen is burned with 25% excess air. Fractional conversions of 90% of the methane
son4ous [18]

Solution :

Consider a mixture of methane and hydrogen.

Take the basis as 100 moles of the mixture.

The mixture contains 75% of methane and 25% of hydrogen by mole and it is burned with 25% in excess air.

Moles of methane = 0.75 x 100

Moles of hydrogen = 0.25 x 100

The chemical reactions involved during the reaction are :

$CH_4+2O_2 \rightarrow CO_2 + 2H_2O$

$CH_4+1.5O_2 \rightarrow CO+2H_2O$

$H_2+0.5O_2 \rightarrow H_2O$

The fractional conversion of methane is 90%

Number of moles of methane burned during the reaction is = 0.9 x 75

                                                                                                   = 67.5

Moles of methane leaving = initial moles of methane - moles of methane burned

                                           = 75 - 67.5

                                           = 7.5 moles

Fractional conversion of hydrogen is 85%

The number of moles of hydrogen burned during the reaction is = 0.85 x 25

                                                                                                   = 21.25

Moles of hydrogen leaving = initial moles of hydrogen - moles of hydrogen burned

                                           = 25 - 21.25

                                           = 3.75 moles

Methane undergoing complete combustion is 95%.

$CO_2$ formed is = 0.95 x 67.5

                       = 64.125 moles

$CO$ formed is = 0.05 x 67.5

                       = 3.375 moles

Oxygen required for the reaction is as follows :

From reaction 1, 1 mole of the methane requires 2 moles of oxygen for the complete combustion.

Hence, oxygen required is = 2 x 75

                                            = 150 moles

From reaction 3, 1 mole of the hydrogen requires 0.5 moles of oxygen for the complete combustion.

Hence, oxygen required is = 0.5 x 25

                                            = 12.5 moles

Therefore, total oxygen is = 150 + 12.5 = 162.5 moles

Air is 25% excess.

SO, total oxygen supply = 162.5 x 1.25 = 203.125 moles

Amount of nitrogen = $203.125 \times \frac{0.79}{0.21} $

                                = 764.136 moles

Total oxygen consumed = oxygen consumed in reaction 1 + oxygen consumed in reaction 2 + oxygen consumed in reaction 3

Oxygen consumed in reaction 1 :

1 mole of methane requires 2 moles of oxygen for complete combustion

 = 2 x 64.125

 = 128.25 moles

1 mole of methane requires 1.5 moles of oxygen for partial combustion

= 1.5 x 3.375

= 5.0625 moles

From reaction 3, 1 mole of hydrogen requires 0.5 moles of oxygen

= 0.5 x 21.25

= 10.625 moles.

Total oxygen consumed = 128.25 + 5.0625 + 10.625

                                        = 143.9375 moles

Total amount of steam = amount of steam in reaction 1 + amount of steam in reaction 2 + amount of steam in reaction 3

Amount of steam in reaction 1 = 2 x 64.125 = 128.25 moles

Amount of steam in reaction 2 = 2 x 3.375 = 6.75 moles

Amount of steam in reaction 3  = 21.25 moles

Total amount of steam = 128.25 + 6.75 + 21.25

                                     = 156.25 moles

The composition of stack gases are as follows :

Number of moles of carbon dioxide = 64.125 moles

Number of moles of carbon dioxide = 3.375 moles

Number of moles of methane = 7.5 moles

Number of moles of steam = 156.25 moles

Number of moles of nitrogen = 764.136 moles

Number of moles of unused oxygen = 59.1875 moles

Number of moles of unused hydrogen = 3.75 moles

Total number of moles of stack  gas

= 64.125+3.375+7.5+156.25+764.136+59.1875+3.75

= 1058.32 moles

Concentration of carbon monoxide in the stack gases is

$=\frac{3.375}{1058.32} \times 10^6$

= 3189 ppm

b).  The amount of carbon monoxide in the stack gas can be decreased by increasing the amount of the excess air. As the amount of the excess air increases, the amount of the unused oxygen and nitrogen in the stack gases will increase and the concentration of CO will decrease in the stack gas.  

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3 years ago
Why is this flower able to self-pollinate
Andrei [34K]

Answer:

A flower is self-pollinated if pollen is transferred to it from any flower of the same plant and cross-pollinated if the pollen comes from a flower on a different plant.

Explanation:

This is because each flower is capable of fertilizing itself by autogamy. Autogamy means that the male part of a flower sends pollen to the female part of the same flower.

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3 years ago
Sprinkler powder on the carron board _________ friction​
VARVARA [1.3K]

Answer:

Sprinkling of powder on the carom board <u>reduces</u> friction.

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3 years ago
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A chemist adds of a M zinc nitrate solution to a reaction flask. Calculate the mass in grams of zinc nitrate the chemist has add
weqwewe [10]

corrected question: A chemist adds 135mL of a 0.21M zinc nitrate solution to a reaction flask. Calculate the mass in grams of zinc nitrate the chemist has added to the flask. Round your answer to significant digits.

Answer:

5.37g

Explanation:

0.21M means ; 0.21mol/dm³

1dm³=1L , so we can say 0.21mol/L

if 0.21mol of Zinc nitrate is contained in 1L of water

x   will be contained in 135mL of water

x= 0.21*135*10³/1

=0.02835moles

number of moles=  mass/ molar mass

mass= number of moles *molar mas

molar mass of Zn(NO₃)₂=189.36 g/mol

mass= 0.02835 *189.36

mass=5.37g

3 0
3 years ago
Which statement about states of matter is correct? (1 point)
belka [17]

Answer:

C

Explanation:

If you add enough heat to a solid it eventually becomes a liquid

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