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KiRa [710]
3 years ago
8

Construct a simulated 1H NMR spectrum, including proton integrations, for CH3OC(CH2OCH3)3 (see Hint). Drag the appropriate split

ting patterns to the approximate chemical shift positions; place the integration values in the small bins above the associated chemical shift. Splitting patterns and integrations may be used more than once, or not at all, as needed. Likewise, some bins might remain blank. Note that peak heights are arbitrary and do not indicate proton integrations.

Chemistry
1 answer:
CaHeK987 [17]3 years ago
4 0

Answer:

The drawing of the structure is found in diagram 1 of the attached figure.

Explanation:

Diagram 1 shows that three different types of protons are found in the structure. The nine hydrogen atoms have a similar behavior, the six hydrogen atoms also have a similar behavior and finally, the three hydrogen atoms adjacent to oxygen have a similar behavior. The number of peaks are as follows:

9H = singlet peak = between 3 and 4 ppm

6H = singlet peak = 4 ppm

3H = singlet peak = 3 ppm.

The 9 protons are around 3.5 ppm and the 6 hydrogen atoms show a peak at 4 ppm, and finally, the 3 protons have a peak around 3 ppm. Therefore, the corresponding drawing can be seen in diagram 2.

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3 years ago
Suppose a 250. mL flask is filled with 0.30 mol of N_2 and 0.70 mol of NO. The following reaction becomes possible:N_2(g) +O2 →
Inessa [10]

Answer:

0.4 M

Explanation:

Equilibrium occurs when the velocity of the formation of the products is equal to the velocity of the formation of the reactants. It can be described by the equilibrium constant, which is the multiplication of the concentration of the products elevated by their coefficients divided by the multiplication of the concentration of the reactants elevated by their coefficients. So, let's do an equilibrium chart for the reaction.

Because there's no O₂ in the beginning, the NO will decompose:

N₂(g) + O₂(g) ⇄ 2NO(g)

0.30 0 0.70 Initial

+x +x -2x Reacts (the stoichiometry is 1:1:2)

0.30+x x 0.70-2x Equilibrium

The equilibrium concentrations are the number of moles divided by the volume (0.250 L):

[N₂] = (0.30 + x)/0.250

[O₂] = x/0.25

[NO] = (0.70 - 2x)/0.250

K = [NO]²/([N₂]*[O₂])

K = \frac{(\frac{0.70 -2x}{0.250})^2 }{\frac{0.30+x}{0.250}*\frac{x}{0.250} }

7.70 = (0.70-2x)²/[(0.30+x)*x]

7.70 = (0.49 - 2.80x + 4x²)/(0.30x + x²)

4x² - 2.80x + 0.49 = 2.31x + 7.70x²

3.7x² + 5.11x - 0.49 = 0

Solving in a graphical calculator (or by Bhaskara's equation), x>0 and x<0.70

x = 0.09 mol

Thus,

[O₂] = 0.09/0.250 = 0.36 M ≅ 0.4 M

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