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Nonamiya [84]
3 years ago
14

Compound A has the molecular formula C14H25Br and was obtained by reaction of sodium acetylide with 1,12-dibromododecane. On tre

atment of compound A with sodium amide, it was converted to compound B (C14H24). Ozonolysis of compound B gave the compound with the following chemical formula: HO2C(CH2)12COOH (a diacid because it has two acid functional groups on each end). Catalytic hydrogenation of compound B over Lindar palladium gave compound C (C14H26) and hydrogenation of compound B over platinum gave compound D (C14H28). Sodium-ammonia reaction of compound B gave compound E (C14H26). Both C and E yielded O=CH(CH2)12CH=O on ozonolysis. Assign structures to compounds A through E so as to be consistent with the observed transformations.

Chemistry
1 answer:
RUDIKE [14]3 years ago
4 0

Answer:

Look at the pictures. On the 1 are compounds A and B. Compound c from b is on the 2nd image. Compound D is on 3rd image. Compound E is the same for compound C.

Explanation:

So for compound A sodium acetylide substitutes nucleophilicaly one Br on 1,12-dibromododecane. Then to obtain compound B sodium amide eliminates another Br. So for acetylene and alkene groups ozonolysis works the same way and we obtain diacid. Lyndlar catalyst works only on alkynes and make cis-alkenes from them. but we have a terminal alkyne for wich no isomers may occur. Pt reduction provides alkanes from both alenes and akynes. And sodium ammonia reduction works only on alkynes to provide trans-alkenes but, as I've said, isomers are not our case. So compounds E and C are the same and undergo same reaction with ozone.

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Write the fraction of the mass of kcl produced from 1 g of k2c03​
Minchanka [31]

Mass of KCl= 1.08 g

<h3>Further explanation</h3>

Given

1 g of K₂CO₃

Required

Mass of KCl

Solution

Reaction

K₂CO₃ +2HCl ⇒ 2KCl +H₂O + CO₂

mol of K₂CO₃(MW=138 g/mol) :

= 1 g : 138 g/mol

= 0.00725

From the equation, mol ratio K₂CO₃ : KCl = 1 : 2, so mol KCl :

= 2/1 x mol K₂CO₃

= 2/1 x 0.00725

= 0.0145

Mass of KCl(MW=74.5 g/mol) :

= mol x MW

= 0.0145 x 74.5

= 1.08 g

6 0
3 years ago
What is the movement of water up a narrow tube due to attractions with the surface of the tube called? capillary action meniscus
Shtirlitz [24]

The attraction mediated flow of water in the narrow tube has been termed as Capillary action. Thus, option A is correct.

The process of flowing up of liquid with the attraction force between the molecules and the surface has been achieved with the surface characteristics.

<h3>Movement of water in a narrow tube</h3>

The surface has the force of attraction with the flowing liquids in the sample. It results in the increased surface interaction, and the liquid flows up in the tube against gravity.

The movement of the liquid in the water through a narrow tube has been termed as capillary action. Thus, option A is correct.

Learn more about movement of water, here:

brainly.com/question/1295312

6 0
2 years ago
What is the relationship between the internal energy of a substance and its particle movement?
ss7ja [257]

Answer: The closeness, arrangement and motion of the particles in a substance change when it changes state. Materials are a store of internal energy , due to the motion of particles and the chemical bonds between them. When a substance is heated, its internal energy increases: the movement of its particles increases.

Explanation:

6 0
3 years ago
Ionic formula for sodium oxide
Bas_tet [7]
The ionic formula of sodium oxide would be Na20
5 0
3 years ago
2 bromocyclopentanamine structural formula
Elis [28]

Answer:

The structure is given in attached file.

Explanation:

Explanation

2-bromocyclopentamine (Figure attached) is a synthetic compound which is synthesized by substitution reaction of cyclopentamine and hydrobromide. Its molecular formula and molecular mass are C5H10NBr and 164.05 mol/g respectively.  It is a very reactive compound so it doesn’t available in pure form, it is present in market as a mixture of 2-bromocyclopentamine and Hydrobromide.

Properties :

Its boiling point is 115 0C

Its melting point is – 75 oC

It is highly flammable

It is highly toxic

It is irritant

It is corrosive in nature

5 0
3 years ago
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