1) Chemical equation
16Fe(s) + 3S8(s) ---> 8Fe2S3
2) Molar ratios:
16 mol Fe : 3 mole S8 : 8 mol Fe2S3
3) Convert masses in grams to number of moles
number of moles = mass in grams / molar mass
a) iron, Fe
mass = 3.0 g
atomic mass = 55.845 g/mol
=> number of moles of Fe = 3.0g / 55.845 g/mol = 0.0537 mol
b) Sulfur, S8
mass = 2.5 g
molar mass = 8*32.065 g/mol = 256.52 g/mol
=> number of moles of S8 = 2.5g / 256.52 g/mol = 0.009746 mol
4) Limiting reactant
Theoretical ratio actual ratio
16 mol Fe / 3 mol S8 0.0537 mol Fe / 0.009746 mol S8
5.33 5.50
So, there is a little bit more Fe than the theoretical needed to react all the S8, which means the S8 is the limiting reactant.
5) Calculate the number of moles of iron (III) produced with 2.5 g (0.009746 moles) of S8
3moles S8 / 8 moles Fe2S3 = 0.009746 moles S8 / x
=> x = 0.009746 * 8 / 3 moles Fe2S3 = 0.026 moles Fe2S3
6) Convert 0.026 moles Fe2S3 into grams
mass in grams = number of moles * molar mass
molar mass of Fe2S3 = 207.9 g/mol
mass = 0.026 mol * 207.9 g/mol = 5.40 g
7) Answer: option D)
Answer: The new volume of a 61 L sample at STP that is moved to 183 K and 0.60 atm is 54.63 L.
Explanation:
Given:
= 61 L,
= 183 K,
= 0.60 atm
At STP, the value of pressure is 1 atm and temperature is 273.15 K.
Now, formula used to calculate the new volume is as follows.

Substitute the values into above formula as follows.

Thus, we can conclude that the new volume of a 61 L sample at STP that is moved to 183 K and 0.60 atm is 54.63 L.
A scientist would most likely need to update her model when it no longer supports the latest results.
Answer : The final equilibrium temperature of the water and iron is, 537.12 K
Explanation :
In this problem we assumed that heat given by the hot body is equal to the heat taken by the cold body.


where,
= specific heat of iron = 560 J/(kg.K)
= specific heat of water = 4186 J/(kg.K)
= mass of iron = 825 g
= mass of water = 40 g
= final temperature of water and iron = ?
= initial temperature of iron = 
= initial temperature of water = 
Now put all the given values in the above formula, we get:


Therefore, the final equilibrium temperature of the water and iron is, 537.12 K
I thinking the limitation is that a shifting electron will always move from a more excited states to a less excited state. Electrons could not circle the nucleus because they would lose energy by emitting electromagnetic radiation and spiral into the nucleus. In addition Bohr was not able to explain electrons orbits of large atom w/many electrons.