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Sholpan [36]
3 years ago
15

A 25.0 mL aliquot of 0.0430 0.0430 M EDTA EDTA was added to a 56.0 56.0 mL solution containing an unknown concentration of V 3 +

V3+ . All of the V 3 + V3+ present in the solution formed a complex with EDTA EDTA , leaving an excess of EDTA EDTA in solution. This solution was back-titrated with a 0.0490 0.0490 M Ga 3 + Ga3+ solution until all of the EDTA EDTA reacted, requiring 13.0 13.0 mL of the Ga 3 + Ga3+ solution. What was the original concentration of the V 3 + V3+ solution?
Chemistry
1 answer:
Nady [450]3 years ago
4 0

Answer:

Check the explanation

Explanation:

As we know the reaction of  EDTA and Ga^3+ and EDTA and V^3+

Let us say that the ratio is 1:1

Therefore, the number of moles of Ga^3+ = molarity * volume

                                    = 0.0400M * 0.011L

                                    = 0.00044 moles

Therefore excess EDTA moles = 0.00044 moles

Given , initial moles of EDTA  = 0.0430 M * 0.025 L

                                        = 0.001075

Therefore reacting moles of EDTA with V^3+ = 0.001075 - 0.00044 = 0.000675 moles

Let us say that the ratio between V^3+ and EDTA is 1:1

Therefore moles of V^3+ = 0.000675 moles

Molarity = moles / volume

                                    = 0.000675 moles / 0.057 L

                                    = 0.011 M (answer).

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