Which statement below correctly describes the relationship between Q and K for both reactions? Are these reactions spontaneous a
1 answer:
Answer:
Q < K for both reactions. Both are spontaneous at those concentrations of substrate and product.
Explanation:
Hello,
In this case, the undergoing chemical reactions with their proper Gibbs free energy of reaction are:
The cellular concentrations are as follows: [A] = 0.050 mM, [B] = 4.0 mM, [C] = 0.060 mM and [D] = 0.010 mM.
For each case, the reaction quotient is:
A typical temperature at a cell is about 30°C, in such a way, the equilibrium constants are:
Therefore, Q < K for both reactions. Both are spontaneous at those concentrations of substrate and product.
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Answer : The correct rate law for the reaction is,
Explanation :
Rate law : It is defined as the expression which expresses the rate of the reaction in terms of molar concentration of the reactants with each term raised to the power their stoichiometric coefficient of that reactant in the balanced chemical equation.
For the given chemical equation:
Rate law expression for the reaction:
where,
a = order with respect to
b = order with respect to
Expression for rate law for first observation:
....(1)
Expression for rate law for second observation:
....(2)
Expression for rate law for third observation:
....(3)
Expression for rate law for fourth observation:
....(4)
Dividing 1 from 2, we get:
Dividing 2 from 3, we get:
Calculation used :
Thus, the rate law becomes:
Answer: Option (c) is the correct answer.
Explanation:
When an acid or base is added to a solution then any resistance by the solution in changing the pH of the solution is known as a buffer.
This is because a buffer has the ability to not get affected by the addition of small amounts of an acid or a base. As a result, it helps in maintaining the pH of the solution.
In the give case, when we add the HCl then more number of protons will dissociate. This causes the acetate to react with the protons and leads to the formation of acetic acid.
We know that acetic acid is a weak acid and it dissociates partially or feebly. Therefore, no change in pH will take place.
Thus, we can conclude that equation represents the chemical reaction that accounts for the fact that acid was added but there was no detectable change in pH.