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Naily [24]
3 years ago
13

A solution containing a mixture of metal cations was treated with dilute HCl and no precipitate formed. Next, H2S was bubbled th

rough the acidic solution. A precipitate formed and was filtered off. Then, the pH was raised to about 8 and H2S was again bubbled through the solution. A precipitate again formed and was filtered off. Finally, the solution was treated with a sodium carbonate solution, which resulted in no precipitation. Which metal ions were definately present, which were definitely absent, and which may or may not have been present in the original mixture?Ag+, Ba2+, Mg2+, Hg2+, Pb2+, Hg2^2+, Cu2+, Zn2+, Ni2+, Co2+, Sn2+, Li+, Sb3+
Chemistry
1 answer:
erica [24]3 years ago
5 0

Answer:

Explanation:

  Ions which will  be definitely  absent -

Ag⁺ , Hg₂⁺ , Pb⁺², because their chlorides are insoluble in water.

Ba⁺² ,Ca⁺² because their carbonates are insoluble in water,

Ions which will be definitely present  

Cu⁺² , Pb⁺² . Hg⁺² , Sb⁺³ , Sn⁺² , because their sulphides are insoluble at pH = 8.

For the rest nothing can be said.

 

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The maximum mass of anhydrous zinc chloride that could be obtained from the products of the reaction is 8.18 g

<h3>Stoichiometry </h3>

From the question, we are to determine the maximum mass of anhydrous zinc chloride that could be obtained

From the given balanced chemical equation,

ZnO + 2HCl → ZnCl₂ + H₂O

This means 1 mole of ZnO will completely react with 2 moles of HCl to produce 1 mole of ZnCl₂ and 1 mole of H₂O

From the given information

Number of moles of ZnO = 0.0830 mole

Now, we will calculate the number of moles of HCl that is present

Volume of HCl added = 100 cm³ = 0.1 dm³

Concentration of the HCl = 1.20 mol/dm³

Using the formula,

Number of moles = Concentration × Volume

Number of moles of HCl present = 1.20 × 0.1 = 0.120 mole

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1 mole of ZnO will completely react with 2 moles of HCl to produce 1 mole of ZnCl₂

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0.06 mole of ZnO will react with the 0.120 mole of HCl to produce 0.06 mole of ZnCl₂

Therefore, maximum number of moles of anhydrous zinc chloride that could be produced is 0.06 mole

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Mass ≅ 8.18 g

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