Question

Silicon halides have stronger bonds than corresponding carbon halides. Which of the following is a possible explanation of this phenomenon
Silicon has the ability to form a partial double bond with a halogen through the overlap of its d-orbital with a p-orbital of the halogen

Answer 1

Answer:

Correct answer is (C) Silicon has the ability to form a partial double bond with a halogen through the overlap of its d-orbital with a p-orbital of the halogen

You question did not complete as the options are missing. See the options below;

A) The larger silicon atoms permit better overlap of its atomic orbitals with those of the halogens than the smaller carbons atoms do.

B) The large electronegativity difference between silicon and the halogens makes their bonds stronger than those of carbon.

C) Silicon has the ability to form a partial double bond with a halogen through the overlap of its d-orbital with a p-orbital of the halogen.

D) Silicon has a larger effective nuclear charge than carbon which allows it to bond more strongly to the more negative halogens than carbon.

E) Carbon-halogen bonds are unusually weak

Explanation:

Silicon reacts vigorously with halogens to form siliconhalides. The d subshell has 5 orbitals and halogen carries seven valence electronics with 5 in its p-orbital. When they react, they form stronger bonding than carbonhalide