Answers and Explanation:
a)- The chemical equation for the corresponden equilibrium of Ka1 is:
2. HNO2(aq)⇌H+(aq)+NO−2
Because Ka1 correspond to a dissociation equilibrium. Nitrous acid (HNO₂) losses a proton (H⁺) and gives the monovalent anion NO₂⁻.
b)- The relation between Ka and the free energy change (ΔG) is given by the following equation:
ΔG= ΔGº + RT ln Q
Where T is the temperature (T= 25ºc= 298 K) and R is the gases constant (8.314 J/K.mol)
At the equilibrium: ΔG=0 and Q= Ka. So, we can calculate ΔGº by introducing the value of Ka:
⇒ 0 = ΔGº + RT ln Ka
ΔGº= - RT ln Ka
ΔGº= -8.314 J/K.mol x 298 K x ln (4.5 10⁻⁴)
ΔGº= 19092.8 J/mol
c)- According to the previous demonstation, at equilibrium ΔG= 0.
d)- In a non-equilibrium condition, we have Q which is calculated with the concentrations of products and reactions in a non equilibrium state:
ΔG= ΔGº + RT ln Q
Q= ((H⁺) (NO₂⁻))/(HNO₂)
Q= ( (5.9 10⁻² M) x (6.7 10⁻⁴ M) ) / (0.21 M)
Q= 1.88 10⁻⁴
We know that ΔGº= 19092.8 J/mol, so:
ΔG= ΔGº + RT ln Q
ΔG= 19092.8 J/mol + (8.314 J/K.mol x 298 K x ln (1.88 10⁻⁴)
ΔG= -2162.4 J/mol
Notice that ΔG<0, so the process is spontaneous in that direction.
Explanation:
Since HF is a weak acid, the use of an ICE table is required to find the pH. The question gives us the concentration of the HF.
HF+H2O⇌H3O++F−HF+H2O⇌H3O++F−
Initial0.3 M-0 M0 MChange- X-+ X+XEquilibrium0.3 - X-X MX M
Writing the information from the ICE Table in Equation form yields
6.6×10−4=x20.3−x6.6×10−4=x20.3−x
Manipulating the equation to get everything on one side yields
0=x2+6.6×10−4x−1.98×10−40=x2+6.6×10−4x−1.98×10−4
Now this information is plugged into the quadratic formula to give
x=−6.6×10−4±(6.6×10−4)2−4(1)(−1.98×10−4)−−−−−−−−−−−−−−−−−−−−−−−−−−−−√2x=−6.6×10−4±(6.6×10−4)2−4(1)(−1.98×10−4)2
The quadratic formula yields that x=0.013745 and x=-0.014405
However we can rule out x=-0.014405 because there cannot be negative concentrations. Therefore to get the pH we plug the concentration of H3O+ into the equation pH=-log(0.013745) and get pH=1.86
Number 9 adding oil lubricates the chain making it easier to pedal. Also the oil prevents rusting
MgCl2 would be magnesium chloride.
Here's three i can name off the top of my head.
Physics , Chemistry and Biology are all real types of science.
