The right answer is 2.
The number of protons contained in a nucleus (called an atomic number) is characteristic of a chemical element. For a given atomic number, the number of neutrons defines different "types" of this element: isotopes. The variation of the number of protons of the nucleus of an atom, during a nuclear reaction for example, causes a change of the element studied.
Yes, you're right the answer is 0,02 moles.
Grams of Phosphorus = 4.14 grams
Grams of white compound = 27.8 grams
Grams of Chlorine would be = 27.8 - 4.14 = 23.66 grams
Calculating moles which would be grams / molar mass
Molar mass of P = 30.97 grams / moles; Molar mass of Cl = 35.45 grams / moles
Moles of Phosphorus = 4.14 grams / 30.97 grams / moles = 0.1337 moles
Moles of Chlorine = 23.66 grams / 35.45 grams / moles = 0.6674 moles
Calculating the ratios by dividing with the small entity
P = 0.1337 moles / 0.1337 moles = 1
Cl = 0.6674 moles / 0.1337 moles = 5
So the empirical formula would be PCl5