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Savatey [412]
3 years ago
11

Calculate the work (kJ) done during a reaction in which the internal volume expands from 28 L to 51 L against an outside pressur

e of 4.9 atm.
Chemistry
1 answer:
gayaneshka [121]3 years ago
4 0

Answer:

W= -11KJ

Explanation:

Given:

volume expands from 28 L to 51 L

pressure =4.9 atm.

We will need to Convert the pressure to Pascal SI

But 1 atm = 101,325 Pa.

Then,

Pressure= (4.9*101323)/1atm = 5*10^5 pa

Then we need to Convert the volumes to cubic meters

But we know that1 m³ = 1,000 L.

V1= 28L * 1m^3/1000L = 0.028m^3

V2=51L × 1m^3 /1000L =0.051m^3

The work done during the expansion of a gas can be calculated as

W= -P(V2-V1)

W= - 5*10^5(0.051m^3 - 0.028m^3)

W= -1.1× 10^4J

Then we can Convert the work to kiloJoule

But1 kJ = 1,000 J.

W= -1.1× 10^4J× 1kj/1000J

= -11KJ

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Based on the equation, how many grams of Br2 are required to react completely with 36.2 grams of AlCl3?
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Answer:

65.08 g.

Explanation:

  • For the reaction, the balanced equation is:

<em>2AlCl₃ + 3Br₂ → 2AlBr₃ + 3Cl₂,</em>

2.0 mole of AlCl₃ reacts with 3.0 mole of Br₂ to produce 2.0 mole of AlBr₃ and 3.0 mole of Cl₂.

  • Firstly, we need to calculate the no. of moles of 36.2 grams of AlCl₃:

<em>n = mass/molar mass</em> = (36.2 g)/(133.34 g/mol) = <em>0.2715 mol.</em>

<u><em>Using cross multiplication:</em></u>

2.0 mole of AlCl₃ reacts with → 3.0 mole of Br₂, from the stichiometry.

0.2715 mol of AlCl₃ reacts with → ??? mole of Br₂.

∴ The no. of moles of Br₂ reacts completely with 0.2715 mol (36.2 g) of AlCl₃  = (0.2715 mol)(3.0 mole)/(2.0 mole) = 0.4072 mol.

<em>∴ The mass of Br₂ reacts completely with 0.2715 mol (36.2 g) of AlCl₃ = no. of moles of Br₂ x molar mass</em> = (0.4072 mol)(159.808 g/mol ) = <em>65.08 g.</em>

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