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ad-work [718]
2 years ago
8

In a study of the following reaction at 1200 K it was observed that when the equilibrium partial pressure of water vapor is 15.0

torr, the total pressure at equilibrium is 36.3 torr.
Chemistry
1 answer:
raketka [301]2 years ago
7 0

The question is incomplete , the complete question is ;

In a study of the following reaction :

3Fe(s)+4H_2O(g)\rightleftharpoons Fe_2O_4(s)+4H_2(g)

at 1200 K it was observed that when the equilibrium partial pressure of water vapor is 15.0 torr, the total pressure at equilibrium is 36.3 torr. Calculate the K_p foe this reaction at 1200 K.

Answer:

The K_p for this reaction at 1200 K is 4.066[/tex].

Explanation:

Partial pressure of the water vapor at equilibrium = p_1=15.0 Torr

Partial pressure of the hydrogen gas at equilibrium  = p_2

Total pressure at equilibrium = P=36.3 Torr

P_1+P_2

p_2=P-P_1=36.3 Torr-15.0 Torr=21.3 Torr

3Fe(s)+4H_2O(g)\rightleftharpoons Fe_2O_4(s)+4H_2(g)

The expression if K_p is given as;

K_p=\frac{(p_2)^4}{(p_1)^4}

(the partial pressure of the gas will be taken along with which partial pressure of the solids are taken as unity)

K_p=\frac{(21.3 Torr)^4}{(15.0 Torr)^4}

K_p=4.066

The K_p for this reaction at 1200 K is 4.066[/tex].

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Which of the following statements is true about an endergonic reaction? ∆G is positive ∆G is negative ∆S is negative
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2 years ago
Using the data, which of the following is the rate constant for the rearrangement of methyl isonitrile at 320 °C? (HINT: the act
algol13

Answer:

D) 2.3 x 10⁻¹ s⁻¹

Explanation:

The rate constant is related to the activation energy through the formula:

k= Ae^(-Eₐ /RT)

where A is the collision factor, Eₐ the activation energy, R is the gas constant ( 8.314 J/Kmol ) , and T is the temperature (K)

So a plot of lnk versus 1/T ( Arrehenius plot ) gives us a straight line with slope equal -Eₐ/R and intercept lnA

lnk = -(Eₐ/T)(1/T) + lnA

which has the form y= mx + b

In this problem, we can use the data provided to:

a) Using a calculator determine the slope and intercept and then calculate the value of rate constant at 320 ºC, or

b) Plot the data and determine the equation of the best line , and answer the question for k @ 320 ºC by reading the value from the plot.

Once you do the plot, the resulting equation is:

y = - 19 x 10³ x + 30,582 ( R² = 0.999 )

So for T = 320 + 273 K = 593 K

Y = 19 x 10³ X + 30.58

So for T = (320 + 273)K = 593 K

Y =  -19 x 10³ ( 1/593) + 30.58 = -32.04 +30.58 = - 1.46

and then since

y = lnk ⇒ e^y = k

k= e^-1.46 = 2.3 x 10⁻¹ s⁻¹

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