Electronegativity is the strength an atom has to attract a bonding pair of electrons to itself. When a chlorine atom covalently bonds to another chlorine atom, the shared electron pair is shared equally. The electron density that comprises the covalent bond is located halfway between the two atoms.
But what happens when the two atoms involved in a bond aren’t the same? The two positively charged nuclei have different attractive forces; they “pull” on the electron pair to different degrees. The end result is that the electron pair is shifted toward one atom.
ATTRACTING ELECTRONS: ELECTRONEGATIVITIES
The larger the value of the electronegativity, the greater the atom’s strength to attract a bonding pair of electrons. The following figure shows the electronegativity values of the various elements below each element symbol on the periodic table. With a few exceptions, the electronegativities increase, from left to right, in a period, and decrease, from top to bottom, in a family.
Electronegativities give information about what will happen to the bonding pair of electrons when two atoms bond. A bond in which the electron pair is equally shared is called a nonpolar covalent bond. You have a nonpolar covalent bond anytime the two atoms involved in the bond are the same or anytime the difference in the electronegativities of the atoms involved in the bond is very small.

Now consider hydrogen chloride (HCl). Hydrogen has an electronegativity of 2.1, and chlorine has an electronegativity of 3.0. The electron pair that is bonding HCl together shifts toward the chlorine atom because it has a larger electronegativity value.
A bond in which the electron pair is shifted toward one atom is called a polar covalent bond. The atom that more strongly attracts the bonding electron pair is slightly more negative, while the other atom is slightly more positive. The larger the difference in the electronegativities, the more negative and positive the atoms become.
Now look at a case in which the two atoms have extremely different electronegativities — sodium chloride (NaCl). Sodium chloride is ionically bonded. An electron has transferred from sodium to chlorine. Sodium has an electronegativity of 1.0, and chlorine has an electronegativity of 3.0.
That’s an electronegativity difference of 2.0 (3.0 – 1.0), making the bond between the two atoms very, very polar. In fact, the electronegativity difference provides another way of predicting the kind of bond that will form between two elements, as indicated in the following table.
Electronegativity DifferenceType of Bond Formed0.0 to 0.2nonpolar covalent0.3 to 1.4polar covalent> 1.5ionic
The presence of a polar covalent bond in a molecule can
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Variations in electronegativity prompt in the unequal halves of electrons in polar molecules because when one atom is more electronegative than the other, it becomes more polar than the other.
It results in the more electronegative atom to have a slightly negative (-ve) charges, and the other atom to have partial or slightly positive(+ve) charges.
Polar molecules have unequal sharing of electrons because the atoms have unequal attraction for electrons so the sharing is unequal.
The larger the difference in electronegativity between the two atoms, the more the polar the bond.
Hydrogen bonds are involved in unequal sharing of electrons between two atoms.
To know more about variations in electronegativity in polar molecules here :
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Answer:
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Explanation:
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The rate constant of the reaction K we can get it from this formula:
K=㏑2/ t1/2 and when we have this given (missing in question):
that we have one jar is labeled t = 0 S and has 16 yellow spheres inside and the jar beside it labeled t= 10 and has 8 yellow spheres and 8 blue spheres and the yellow spheres represent the reactants A and the blue represent the products B
So when after 10 s and we were having 16 yellow spheres as reactants and becomes 8 yellow and 8 blue spheres as products so it decays to the half amount so we can consider T1/2 = 10 s
a) by substitution in K formula:
∴ K = ㏑2 / 10 = 0.069
The amount of A (the reactants) after N half lives = Ao / 2^n
b) so no.of yellow spheres after 20 s (2 half-lives) = 16/2^2 = 4
and the blue spheres = Ao - no.of yellow spheres left = 16 - 4 = 12
c) The no.of yellow spheres after 30 s (3 half-lives) = 16/2^3 = 2
and the blue spheres = 16 - 2 = 14
