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Direct electron transfer from a a singlet reduced species to a triplet oxidizing species is quantum-mechanically forbidden.
<h3><u>Transfer from singlet to triplet:</u></h3>
- Either an excited singlet state or an excited triplet state will occur when an electron in a molecule with a singlet ground state is stimulated (through radiation absorption) to a higher energy level.
- All electron spins in a molecule electronic state known as a singlet are coupled.
- In other words, the ground state electron and the stimulated electron's spin are still coupled (a pair of electrons in the same energy level must have opposite spins, per the Pauli exclusion principle).
- The excited electron and ground state electron are parallel in a triplet state because they are no longer coupled (same spin).
- It is less likely that a triplet state would arise when the molecule absorbs radiation since excitation to a triplet state necessitates an additional "forbidden" spin transfer.
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Explanation:
Answer:
8. the answer is B.
9. the answer is A.
Explanation:
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8. In this case, by bearing to mind that the limiting reactant is always completely consumed and the excess one remain as a leftover at the end of the reaction, we can also infer that as all the limiting reactant is consumed, it must determine the maximum amount of product as the excess reactant will hypothetically produce a greater mass than expected; thus, the answer to this question is B.
9. In this case, since the mole ratio of oxygen to water is 1:2, the following proportional factor is used to calculate the produced mass of water:
Thus, the answer is this case is A.
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Explanation:
Mole ratio of NH3 to NaNH2 = 2 : 2.
Moles of NaNH2 produced
= 4.3mol * (2/2) = 4.3mol.
