Answer:
a) 
b) entropy of the sistem equal to a), entropy of the universe grater than a).
Explanation:
a) The change of entropy for a reversible process:
The energy balance:
![\delta U=[tex]\delta Q- \delta W](https://tex.z-dn.net/?f=%5Cdelta%20U%3D%5Btex%5D%5Cdelta%20Q-%20%5Cdelta%20W)
If the process is isothermical the U doesn't change:
![0=[tex]\delta Q- \delta W](https://tex.z-dn.net/?f=0%3D%5Btex%5D%5Cdelta%20Q-%20%5Cdelta%20W)
The work:
If it is an ideal gas:
Solving:
Replacing:
Given that it's a compression: V2<V1 and ln(V2/V1)<0. So:
b) The entropy change of the sistem will be equal to the calculated in a), but the change of entropy of the universe will be 0 in a) (reversible process) and in b) has to be positive given that it is an irreversible process.
Answer:
in 1983, Lake Mead had a recorded water level of 1,225 feet above sea level. The closest it's been to that level in modern times was in 2000. Explanation:
Answer:D the pressure increases
Explanation:
Answer:
<em><u>=>A Love wave moves sideways along the surface of the earth in a snake-like motion. Like S waves, Love waves do not move through liquid.</u></em>
Answer:
To fulfill octet of B atom in borane, nucleophilic attack by pi electrons of alkene takes place with electrophilic B center in borane.
Explanation:
In Borane (
), B atom has energetically vacant 2p orbital and thereby octet is incomplete.Therefore B center in borane act as an electrophilic center.
In alkene, pi bonding electrons are loosely bound together due to side on overlap of two constituent p-orbitals. Hence this pi bond can be easily broken. Alternatively, we can say that pi bond in alkene act as a potential nucleophile.
The first step of hydroboration occurs in a concerted manner where pi electrons of alkene first attack vacant 2p orbital of B in borane to fulfill it's octet (represented by an arrow drawn from alkene to B atom) and forms a 4 memebered cyclic intermediate. Simulaneously, a B-H bond in borane is donated to alkene through 3c-2e bond (3 center-2 electron bond).
Full mechanism has been shown below.
