Answers and Explanation:
a)- The chemical equation for the corresponden equilibrium of Ka1 is:
2. HNO2(aq)⇌H+(aq)+NO−2
Because Ka1 correspond to a dissociation equilibrium. Nitrous acid (HNO₂) losses a proton (H⁺) and gives the monovalent anion NO₂⁻.
b)- The relation between Ka and the free energy change (ΔG) is given by the following equation:
ΔG= ΔGº + RT ln Q
Where T is the temperature (T= 25ºc= 298 K) and R is the gases constant (8.314 J/K.mol)
At the equilibrium: ΔG=0 and Q= Ka. So, we can calculate ΔGº by introducing the value of Ka:
⇒ 0 = ΔGº + RT ln Ka
ΔGº= - RT ln Ka
ΔGº= -8.314 J/K.mol x 298 K x ln (4.5 10⁻⁴)
ΔGº= 19092.8 J/mol
c)- According to the previous demonstation, at equilibrium ΔG= 0.
d)- In a non-equilibrium condition, we have Q which is calculated with the concentrations of products and reactions in a non equilibrium state:
ΔG= ΔGº + RT ln Q
Q= ((H⁺) (NO₂⁻))/(HNO₂)
Q= ( (5.9 10⁻² M) x (6.7 10⁻⁴ M) ) / (0.21 M)
Q= 1.88 10⁻⁴
We know that ΔGº= 19092.8 J/mol, so:
ΔG= ΔGº + RT ln Q
ΔG= 19092.8 J/mol + (8.314 J/K.mol x 298 K x ln (1.88 10⁻⁴)
ΔG= -2162.4 J/mol
Notice that ΔG<0, so the process is spontaneous in that direction.
Answer:
Li2S> Na2S> K2S> CsS
Explanation:
The lattice energy of ionic species depends on the relative sizes of ions in the ionic compounds. As the size of ions increases, the lattice energy decreases and vice versa.
When the size of the anions are the same, the lattice energy now depends on the relative sizes of the cations. Therefore, since all the compounds are sulphides and the order of magnitude of ionic sizes is: Li^+ < Na^+ < K^+ < Cs^+.
Therefore, the order of decrease in lattice energy is; Li2S> Na2S> K2S> CsS
Answer:
The correct answer is reduction.
Explanation:
Nitrogen gas reacts with hydrogen gas and get reduced to form ammonia. In this reaction.This is important reaction of atmospheric nitrogen fixation.The reaction is carried out by many nitrogen fixing bacteria such as Azotobacter,Clostridium etc.
N2+3H2+6e- = 2NH3
Answer:
A. It's a 'clean' energy. Your cooch need a cleanup
Add an alkaline compound to raise the pH to 7.2.
