Answer:
CH₃CH₂CH₂COOH > CH₃CH₂COOH > ClCH₂CH₂COOH > ClCH₂COOH
Explanation:
Electron-withdrawing groups (EWGs) increase acidity by inductive removal of electrons from the carboxyl group.
Electron-donating groups (EDGs) decrease acidity by inductive donation of electrons to the carboxyl group.
- The closer the substituent is to the carboxyl group, the greater is its effect.
- The more substituents, the greater the effect.
- The effect tails off rapidly and is almost zero after about three C-C bonds.
CH₃CH₂-CH₂COOH — EDG — weakest — pKₐ = 4.82
CH₃-CH₂COOH — reference — pKₐ = 4.75
ClCH₂-CH₂COOH — EWG on β-carbon— stronger — pKₐ = 4.00
ClCH₂COOH — EWG on α-carbon — strongest — pKₐ = 2.87
Answer:
1f 3f 5g 1p 2d
Explanation:
There is only 4f and 5f orbitals.
G is not an orbital.
P orbital starts with 2p
D orbital starts with 3d
Answer:
2.12atm
Explanation:
Boyle's Law: P1V1 = P2V2
Manipulate to solve for unknown: P2 = P1V1/V2
Substitute values: P2=(1.2atm)(4.6L)/2.6L
P2 = 2.1230769atm
Round to 3 sig figs to get 2.12atm
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Answer:
The answer to the question is
The specific heat capacity of the alloy = 1.77 J/(g·°C)
Explanation:
To solve this, we list out the given variables thus
Mass of alloy = 45 g
Initial temperature of the alloy = 25 °C
Final temperature of the alloy = 37 °C
Heat absorbed by the alloy = 956 J
Thus we have
ΔH = m·c·(T₂ - T₁) where ΔH = heat absorbed by the alloy = 956 J, c = specific heat capacity of the alloy and T₁ = Initial temperature of the alloy = 25 °C , T₂ = Final temperature of the alloy = 37 °C and m = mass of the alloy = 45 g
∴ 956 J = 45 × C × (37 - 25) = 540 g·°C×c or
c = 956 J/(540 g·°C) = 1.77 J/(g·°C)
The specific heat capacity of the alloy is 1.77 J/(g·°C)
