The answer should be B: -3
The standard enthalpy of formation for chlorine is zero but the standard entropy is larger than 0 because it is the elemental state of chlorine.
The standard enthalpy of formation for chlorine is zero because cl2 is the elemental state of chlorine and it does not require any energy for the formation of the standard state of chlorine.
The entropy of any system cannot be negative. It can only be positive or zero.
The entropy of a system will become zero only at a absolute zero temperature.
That's why the entropy of chlorine in elemental state is more than zero because absolutely zero temperature can't be obtained.
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(missing in Q) : Calculate the concentration of CO & H2 & H2O when the system returns the equilibrium???
when the reaction equation is:
C(s) + H2O(g) ↔ H2(g) + CO(g)
∴ Kc = [H2] [CO] / [H2O]
and we have Kc = 0.0393 (given missing in the question)
when the O2 is added so, the reaction will be:
2H2(g) + O2(g) → 2H2O(g)
that means that 0.15 mol H2 gives 0.15 mol of H2O
∴ by using ICE table:
[H2O] [H2] [CO]
initial 0.57 + 0.15 0 0.15
change -X +X +X
Equ (0.72-X) X (0.15+X)
by substitution:
0.0393 = X (0.15+X) / (0.72-X) by solving for X
∴ X = 0.098
∴[H2] = X = 0.098 M
∴[CO] = 0.15 + X
= 0.15 + 0.098 = 0.248 M
∴[H2O] = 0.72 - X
= 0.72 - 0.098
= 0.622 M