Answer:
(A) 0.129 M
(B) 0.237 M
Explanation:
(A) The reaction between potassium hydrogen phthalate and barium hydroxide is:
- 2HA + Ba(OH)₂ → BaA₂ + 2H₂O
Where A⁻ is the respective anion of the monoprotic acid (KC₈H₄O₄⁻).
We <u>convert mass of phthalate to moles</u>, using its molar mass:
- 0.978 g ÷ 156 g/mol = 9.27x10⁻³ mol = 9.27 mmol
Now we <u>convert mmol of HA to mmol of Ba(OH)₂</u>:
- 9.27 mmol HA *
= 6.64 mmol Ba(OH)₂
Finally we calculate the molarity of the Ba(OH)₂ solution:
- 6.64 mmol / 35.8 mL = 0.129 M
(B) The reaction between Ba(OH)₂ and HCl is:
- 2HCl + Ba(OH)₂ → BaCl₂ + 2H₂O
So<u> the moles of HCl that reacted </u>are:
- 17.1 mL * 0.129 M *
= 4.41 mmol HCl
And the <u>molarity of the HCl solution is</u>:
- 4.41 mmol / 18.6 mL = 0.237 M
Answer:
CH3CH2NH3+/CH3CH2NH2 would have the largest pKa
Explanation:
To answer this question we must know Kb of CH3CH2NH2 is 5.6x10⁻⁴, and for C6H5NH2 is 4.0x10⁻¹⁰. And the CH3CH2NH3+ and C6H5NH3+ are related with these substances because are their conjugate base. That means:
pKa of CH3CH2NH3+ = CH3CH2NH2; C6H5NH3+ = C6H5NH2
Also, Kw / Kb = Ka
Thus:
pKa of CH3CH2NH3+/CH3CH2NH2 is:
Kw / kb = Ka = 1.79x10⁻¹¹
-log Ka = pKa
pKa = 10.75
pKa of C6H5NH3+/ C6H5NH2 is:
Kw / kb = Ka = 2.5x10⁻⁵
-log Ka = pKa
pKa = 4.6
That means CH3CH2NH3+/CH3CH2NH2 would have the largest pKa
The volume of a sample of ammonia gas : 5.152 L
<h3>Further explanation</h3>
Given
0.23 moles of ammonia
Required
The volume of a sample
Solution
Assumed on STP
Conditions at T 0 ° C and P 1 atm are stated by STP (Standard Temperature and Pressure). At STP, Vm is 22.4 liters / mol.
So for 0.23 moles :
= 0.23 x 22.4 L
= 5.152 L
Answer:
2Li + F₂ → 2LiF
Explanation:
The reaction expression is given as:
Li + F₂ → LiF
We are to balance the expression. In that case, the number of atoms on both sides of the expression must be the same.
Let use a mathematical approach to solve this problem;
Assign variables a,b and c as the coefficients that will balance the expression:
aLi + bF₂ → cLiF
Conserving Li: a = c
F: 2b = c
let a = 1, c = 1 and b = 
Multiply through by 2;
a = 2, b = 1 and c = 2
2Li + F₂ → 2LiF
