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3 years ago

9

Which of the following metal ions is most likely to exist as a stable eight-coordinate complex with fluoride? Cu2+ Cu+ Fe3+ Ag3+

U4+

1 answer:

gtnhenbr [62]3 years ago

7 0

Answer:

U⁴⁺

Explanation:

Fluorine stabilizes metals in higher oxidation states with high M:F ratios.

Hard acids prefer to bind to hard bases.

U⁴⁺ is the hardest acid in the list and F⁻ is a hard base, so an eight-coordinate complex of U⁴⁺ is the most stable.

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A solid mixture consists of 47.6g of KNO3 (potassium nitrate) and 8.4g of K2SO4 (potassium sulfate). The mixture is added to 130

IgorLugansk [536]

<u>Answer:</u> No crystals of potassium sulfate will be seen at 0°C for the given amount.

<u>Explanation:</u>

We are given:

Mass of potassium nitrate = 47.6 g

Mass of potassium sulfate = 8.4 g

Mass of water = 130. g

Solubility of potassium sulfate in water at 0°C = 7.4 g/100 g

This means that 7.4 grams of potassium sulfate is soluble in 100 grams of water

Applying unitary method:

In 100 grams of water, the amount of potassium sulfate dissolved is 7.4 grams

So, in 130 grams of water, the amount of potassium sulfate dissolved will be $\frac{7.4}{100}\times 130=9.62g$

As, the soluble amount is greater than the given amount of potassium sulfate

This means that, all of potassium sulfate will be dissolved.

Hence, no crystals of potassium sulfate will be seen at 0°C for the given amount.

7 0

3 years ago

If the sample contained 2.0 moles of KClO3 at a temperature of 214.0 °C, determine the mass of the oxygen gas produced in grams

Westkost [7]

Answer : The mass of the oxygen gas produced in grams and the pressure exerted by the gas against the container walls is, 96 grams and 1.78 atm respectively.

Explanation : Given,

Moles of $KCl_3$ = 2.0 moles

Molar mass of $O_2$ = 32 g/mole

Now we have to calculate the moles of $MgO$

The balanced chemical reaction is,

$2KClO_3\rightarrow 2KCl+3O_2$

From the balanced reaction we conclude that

As, 2 mole of $KClO_3$ react to give 3 mole of $O_2$

So, 2.0 moles of $KClO_3$ react to give $\frac{2.0}{2}\times 3=3.0$ moles of $O_2$

Now we have to calculate the mass of $O_2$

$\text{ Mass of }O_2=\text{ Moles of }O_2\times \text{ Molar mass of }O_2$

$\text{ Mass of }O_2=(3.0moles)\times (32g/mole)=96g$

Therefore, the mass of oxygen gas produced is, 96 grams.

Now we have to determine the pressure exerted by the gas against the container walls.

Using ideal gas equation:

$PV=nRT\\\\PV=\frac{w}{M}RT\\\\P=\frac{w}{V}\times \frac{RT}{M}\\\\P=\rho\times \frac{RT}{M}$

where,

P = pressure of oxygen gas = ?

V = volume of oxygen gas

T = temperature of oxygen gas = $214.0^oC=273+214.0=487K$

R = gas constant = 0.0821 L.atm/mole.K

w = mass of oxygen gas

$\rho$ = density of oxygen gas = 1.429 g/L

M = molar mass of oxygen gas = 32 g/mole

Now put all the given values in the ideal gas equation, we get:

$P=1.429g/L\times \frac{(0.0821L.atm/mole.K)\times (487K)}{32g/mol}$

$P=1.78atm$

Thus, the pressure exerted by the gas against the container walls is, 1.78 atm.

7 0

2 years ago

Which of the following solutions is acidic? [H3O+] = 1.0 x 10-10 M [H3O+] < 1.0 x 10-7 M [OH-] = 1.0 x 10-10 M [OH-] = 1.0 x

Burka [1]

Answer:

[OH-] = 1.0 x 10-10 M

Explanation:

The acidity of a solution can be determined directly from the concentration of the hydrogen ions and indirectly from the concentrations of the hydroxide ions.

Generally, for a neutral solution we have;

[H3O+] = [OH-] = 1.0 x 10-7 M

For an acidic solution;

[H3O+] > 1.0 x 10-7 M

[OH-] < 1.0 x 10-7 M

Comparing the options the correct option is;

[OH-] = 1.0 x 10-10 M

6 0

2 years ago

Which statement correctly describes the location and charge of the electrons in an atom?

maxonik [38]

Answer:

D

Explanation:

The electrons revolve around the nucleus and they contain negative charge

3 0

2 years ago

Molybdenum (Mo) has a body centered cubic unit cell. The density of Mo is 10.28 g/cm3. Determine (a) the edge length of the unit

ser-zykov [4K]

<u>Answer:</u>

<u>For a:</u> The edge length of the unit cell is 314 pm

<u>For b:</u> The radius of the molybdenum atom is 135.9 pm

<u>Explanation:</u>

<u>For a:</u>

To calculate the edge length for given density of metal, we use the equation:

$\rho=\frac{Z\times M}{N_{A}\times a^{3}}$

where,

$\rho$ = density = $10.28g/cm^3$

Z = number of atom in unit cell = 2 (BCC)

M = atomic mass of metal (molybdenum) = 95.94 g/mol

$N_{A}$ = Avogadro's number = $6.022\times 10^{23}$

a = edge length of unit cell =?

Putting values in above equation, we get:

$10.28=\frac{2\times 95.94}{6.022\times 10^{23}\times (a)^3}\\\\a^3=\frac{2\times 95.94}{6.022\times 10^{23}\times 10.28}=3.099\times 10^{-23}\\\\a=\sqrt[3]{3.099\times 10^{-23}}=3.14\times 10^{-8}cm=314pm$

Conversion factor used: $1cm=10^{10}pm$

Hence, the edge length of the unit cell is 314 pm

<u>For b:</u>

To calculate the edge length, we use the relation between the radius and edge length for BCC lattice:

$R=\frac{\sqrt{3}a}{4}$

where,

R = radius of the lattice = ?

a = edge length = 314 pm

Putting values in above equation, we get:

$R=\frac{\sqrt{3}\times 314}{4}=135.9pm$

Hence, the radius of the molybdenum atom is 135.9 pm

4 0

2 years ago