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balandron [24]
4 years ago
9

Express the concentration of a 0.0350 M aqueous solution of fluoride, F − , in mass percentage and in parts per million (ppm). A

ssume the density of the solution is 1.00 g/mL.a. Number in percentage ....%
b. Number in ppm ........ppm.
Chemistry
1 answer:
sveta [45]4 years ago
7 0

Answer :

(a) The mass percentage is 0.0665 %

(b) The concentration in ppm is 665 ppm.

Explanation :

<u>Part (a) :</u>

As we are given that, 0.0350 M aqueous solution of fluoride ion that means 0.0350 moles of fluoride ion present in 1 L of solution.

First we have to calculate the mass of fluoride ion.

\text{Mass of }F^-=\text{Moles of }F^-\times \text{Molar mass of }F^-

Molar mass of F^- = 19 g/mole

\text{Mass of }F^-=0.0350mol\times 19g/mol=0.665g

Now we have to calculate the mass of solution.

Mass of solution = Density of solution × Volume of solution

Density of solution = 1.00 g/mL

Volume of solution = 1 L = 1000 mL

Mass of solution = 1.00 g/mL × 1000 mL

Mass of solution = 1000 g

Now we have to calculate the mass -percentage.

\text{Mass of percentage}=\frac{\text{Mass of }F^-}{\text{Mass of solution}}\times 100

\text{Mass of percentage}=\frac{0.665g}{1000g}\times 100=0.0665\%

Thus, the mass percentage is 0.0665 %

<u>Part (b) :</u>

Parts per million (ppm) : It is defined as the mass of a solute present in one million (10^6) parts by the mass of the solution.

Now we have to calculate the concentration in ppm.

\text{Concentration in ppm}=\frac{\text{Mass of }F^-}{\text{Mass of solution}}\times 10^6

\text{Concentration in ppm}=\frac{0.665g}{1000g}\times 10^6=665ppm

Thus, the concentration in ppm is 665 ppm.

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A mixture of 15.0 g of the anesthetic halothane (C2HBrClF3 197.4 g/mol) and 22.6 g of oxygen gas has a total pressure of 862 tor
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Answer : The partial pressure of C_2HBrClF_3 and O_2 are, 84 torr and 778 torr respectively.

Explanation : Given,

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Molar mass of C_2HBrClF_3 = 197.4 g/mole

Molar mass of O_2 = 32 g/mole

First we have to calculate the moles of C_2HBrClF_3 and O_2.

\text{Moles of }C_2HBrClF_3=\frac{\text{Mass of }C_2HBrClF_3}{\text{Molar mass of }C_2HBrClF_3}=\frac{15.0g}{197.4g/mole}=0.0759mole

and,

\text{Moles of }O_2=\frac{\text{Mass of }O_2}{\text{Molar mass of }O_2}=\frac{22.6g}{32g/mole}=0.706mole

Now we have to calculate the mole fraction of C_2HBrClF_3 and O_2.

\text{Mole fraction of }C_2HBrClF_3=\frac{\text{Moles of }C_2HBrClF_3}{\text{Moles of }C_2HBrClF_3+\text{Moles of }O_2}=\frac{0.0759}{0.0759+0.706}=0.0971

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\text{Mole fraction of }O_2=\frac{\text{Moles of }O_2}{\text{Moles of }C_2HBrClF_3+\text{Moles of }O_2}=\frac{0.706}{0.0759+0.706}=0.903

Now we have to partial pressure of C_2HBrClF_3 and O_2.

According to the Raoult's law,

p^o=X\times p_T

where,

p^o = partial pressure of gas

p_T = total pressure of gas

X = mole fraction of gas

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p_{O_2}=X_{O_2}\times p_T

p_{O_2}=0.903\times 862torr=778torr

Therefore, the partial pressure of C_2HBrClF_3 and O_2 are, 84 torr and 778 torr respectively.

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