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jeyben [28]
3 years ago
5

Q3. Which of the following objects are chiral and which are achiral? a

Chemistry
1 answer:
Sergio039 [100]3 years ago
3 0

Answer:

See explanation

Explanation:

In this question, we have to follow the IUPAC rules. Lets analyze each compound:

a. 1-methylbutane

In this compound we have a chain of 5 carbons, so the correct name is <u>Pentane.</u>

b. 1,1,3-trimethylhexane

In this compound, we longest chain is made of 7 carbons, so, we have to use the name "heptane". Carbon one would be the closet one to the methyl group, so the correct name is  <u>2,4-dimethylheptane.</u>

c. 5-octyne

In this case, carbon 1 would be the closet one to the triplet bond. With this in mind, the correct name is <u>oct-3-yne.</u>

d. 2-ethyl-1-propanol

In this compound, we longest chain is made of 4 carbons, so, we have to use the name "butane". Carbon one would be the carbon with the "OH" group, so the correct name is  <u>2-methylbutan-1-ol.</u>

<u>e. 2.2-dimethyl-3-butanol</u>

In this case, carbon 1 would be the closet one to the "OH". With this in mind, the correct name is <u>3,3-dimethylbutan-2-ol.</u>

See figure 1

I hope it helps!

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A) Calculate the osmotic pressure difference between seawater and fresh water. For simplicity, assume thatall the dissolved salt
never [62]

Answer:

a)  Δπ = 1.264 atm

b) W = 128 joules

c)  ΔH >> W  ( a factor greater than 17,000 )

Explanation:

a) The osmotic pressure, π , is determined by :

π = nRT/V, where n= moles of solute

                          R= 0.0821 Latm/kmol

                          T = 300 K

calling π(sw) osmotic pressure for  for sea water and π (fw) for fresh water,

salinity of sea water = 3.5 g / 1L water   (assuming only NaCl for the salts)

salinity of fresh water = 0.5 parts per thousand (range: 0- 0.5 ppt)

πsw = (3.5 g/58.44 g/mol) (0.0821 Latm/Kmol) (300 K ) /1 L = 1.475 atm

πfw = (0.5 g/58.44 g/mol) (0.0821 Latm/Kmol) (300 K ) /1 L = 0.211 atm

d water = 1 g/cm³

Δ π = (1.475 - 0.211) = 1.264 atm

b) W = Δπ V = 1.426 atm x 1L = 1.43 L-atm

1 L-atm = 101.33 j

W =  101.33 j/ Latm x  1.43 Latm = 128 joules

c) ΔH = Q₁ + nΔH vap, where

            Q₁  = heat required to bring the solution from 300 K to boiling, 373 K

            ΔH vap = heat of vaporization

Q = mCΔT = 1000 g x 4.186 j x 73 K = 305.6 j = 0.3056 kj

ΔH vap = (1000 g/ 18 g/mol ) 40.7 kj/mol = 2,261 kj

ΔH =  0.3056 kj + 2,261 kj = 2,261.3 kj

Note = Q << ΔH vap and we could have neglected it.

This result shows why nobody talks about evaporation of sea water to produce fresh water ΔH >> W

6 0
3 years ago
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