For each pair of gases, select one that most likely has the highest rate of effusion. Use the periodic table if necessary
2 answers:
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Explanation:
Sublimation is defined as a process in which solid state of a substance directly changes into vapor or gaseous state without undergoing liquid phase.
For example, naphthalene balls show sublimation at room temperature.
As this process does not cause any change in chemical composition of a substance. Hence, it is known as a physical process.
Similarly, when sublimes readily at
. This shows change in physical state of carbon dioxide is taking place, i.e, from solid to gaseous phase.
Thus, we can conclude that when sublimes readily at
then it means physical properties are usually associated with a compound that undergoes this kind of change.
Answer:
Explanation:
One way to calculate the lattice energy is to use Hess's Law.
The lattice energy U is the energy released when the gaseous ions combine to form a solid ionic crystal:
Li⁺(g) + Cl⁻(g) ⟶ LiCl(s); U = ?
We must generate this reaction rom the equations given.
(1) Li(s) + ½Cl₂ (g) ⟶ LiCl(s); ΔHf° = -409 kJ·mol⁻¹
(2) Li(s) ⟶ Li(g); ΔHsub = 161 kJ·mol⁻¹
(3) Cl₂(g) ⟶ 2Cl(g) BE = 243 kJ·mol⁻¹
(4) Li(g) ⟶Li⁺(g) +e⁻ IE₁ = 520 kJ·mol⁻¹
(5) Cl(g) + e⁻ ⟶ Cl⁻(g) EA₁ = -349 kJ·mol⁻¹
Now, we put these equations together to get the lattice energy.
<u>E/kJ </u>
(5) Li⁺(g) +e⁻ ⟶ Li(g) 520
(6) Li(g) ⟶ Li(s) -161
(7) Li(s) + ½Cl₂(g) ⟶ LiCl(s) -409
(8) Cl(g) ⟶ ½Cl₂(g) -121.5
(9) Cl⁻(g) ⟶ Cl(g) + e⁻ <u>+349</u>
Li⁺(g) + Cl⁻(g) ⟶ LiCl(s) -862
The lattice energy of LiCl is .