Infrared energy is the energy of light between microwave radiation and Ultraviolet radiation
Answer:
A i. Internal energy ΔU = -4.3 J ii. Internal energy ΔU = -6.0 J B. The second system is lower in energy.
Explanation:
A. We know that the internal energy,ΔU = q + w where q = quantity of heat and w = work done on system.
1. In the above q = -7.9 J (the negative indicating heat loss by the system). w = 3.6 J (It is positive because work is done on the system). So, the internal energy for this system is ΔU₁ = q + w = -7.9J + 3.6J = -4.3 J
ii. From the question q = +1.5 J (the positive indicating heat into the system). w = -7.5 J (It is negative because work is done by the system). So, the internal energy for this system is ΔU₂ = q + w = +1.5J + (-7.5J) = +1.5J - 7.5J = - 6.0J
B. We know that ΔU = U₂ - U₁ where U₁ and U₂ are the initial and final internal energies of the system. Since for the systems above, the initial internal energies U₁ are the same, then we say U₁ = U. Let U₁ and U₂ now represent the final energies of both systems in A i and A ii above. So, we write ΔU₁ = U₁ - U and ΔU₂ = U₂ - U where ΔU₁ and ΔU₂ are the internal energy changes in A i and A ii respectively. Now from ΔU₁ = U₁ - U, U₁ = ΔU₁ + U and U₂ = ΔU₂ + U. Subtracting both equations U₁ - U₂ = ΔU₁ - ΔU₂
= -4.3J -(-6.0 J)= 1.7 J. Since U₁ - U₂ > 0 , U₂ < U₁ , so the second system's internal energy increase less and is lower in energy and is more stable.
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We have Kc = 4.2 x 10^-2 (given but missing in the question)
and When the balanced equation for this reaction is:
PCl5(g) ↔ PCl3(g) + Cl2(g)
so, according to the Kc formula:
Kc = the concentration of products / the concentration of the reactants
so, to get the concentration of the reactants in equilibrium, the concentration of the products / the concentration of the reactants should equal the Kc value which is given in the question (missing in your question).
So by substitution in Kc formula:
Kc = [PCl3]*[Cl2] / [PCl5]
4.2 x 10^-2 = 0.18 * 0.25 /[PCl5]
∴[PCl5] = 0.18*0.25 / 4.2x10^-2 = 1.07
So the concentration of the reactants in equilibrim = 1.07
is a polar molecule. So, dipole-dipole force and London dispersion force exists between
is a polar molecule. So, dipole-dipole force and London dispersion force exists between
is a nonpolar molecule. So, London dispersion force exists between