Answer:
Impurities will be trapped in the crystals of the benzoic acid crystallized in this manner.
Explanation:
After benzoic acid is dissolved in hot water, it should have been allowed to cool gradually before it is transferred into an ice bath.
This gradual cooling will aid the separation of impurities so that when the vessel is now submerged in an ice bath, only pure benzoic acid is recrystalized.
If the vessel is immediately submerged into an ice bath, impurities will be trapped in the crystals of the benzoic acid.
<u>Given:</u>
Mass of Ag = 1.67 g
Mass of Cl = 2.21 g
Heat evolved = 1.96 kJ
<u>To determine:</u>
The enthalpy of formation of AgCl(s)
<u>Explanation:</u>
The reaction is:
2Ag(s) + Cl2(g) → 2AgCl(s)
Calculate the moles of Ag and Cl from the given masses
Atomic mass of Ag = 108 g/mol
# moles of Ag = 1.67/108 = 0.0155 moles
Atomic mass of Cl = 35 g/mol
# moles of Cl = 2.21/35 = 0.0631 moles
Since moles of Ag << moles of Cl, silver is the limiting reagent.
Based on reaction stoichiometry: # moles of AgCl formed = 0.0155 moles
Enthalpy of formation of AgCl = 1.96 kJ/0.0155 moles = 126.5 kJ/mol
Ans: Formation enthalpy = 126.5 kJ/mol
Calcula el Tanta por ciento en peso de soluto
Answer:
3.1°C
Explanation:
Using freezing point depression expression:
ΔT = Kf×m×i
<em>Where ΔT is change in freezing point, Kf is freezing point depression constant (5.12°c×m⁻¹), m is molality of the solution and i is Van't Hoff factor constant (1 For I₂ because doesn't dissociate in benzene).</em>
Molality of 9.04g I₂ (Molar mass: 253.8g/mol) in 75.5g of benzene (0.0755kg) is:
9.04g ₓ (1mol / 253.8g) = 0.0356mol I₂ / 0.0755kg = 0.472m
Replacing in freezing point depression formula:
ΔT = 5.12°cm⁻¹×0.472m×1
ΔT = 2.4°C
As freezing point of benzene is 5.5°C, the new freezing point of the solution is:
5.5°C - 2.4°C =
<h3>3.1°C</h3>
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