Answer:
Procedure (2)
Explanation:
Assume the dialyses come to equilibrium in the allotted times.
Procedure (1)
If you are dialyzing 5 mL of sample against 4 L of water, the concentration of NaCl will be decreased by a factor of

Procedure (2)
For the first dialysis, the factor is

After a second dialysis, the original concentration of NaCl will be reduced by a factor of

Procedure (2) is more efficient by a factor of

Answer: Lithium
Explanation:
The ratio for the reaction of Li and water is the same, but there are more moles of water than lithium. Therefore, lithium is the limiting reactant.
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Calcium reacts gently with water to give hydrogen and calcium hydroxide, which is only slightly soluble, thus slows down the reaction.
It will be assumed that hydrochloric acid used is a dilute aqueous solution.
However, calcium reacts with hydrochloric acid to give calcium chloride which is readily soluble in water, and hydrogen, being a typical reaction of relatively active metals with acids.
Ca(s) + 2HCl(aq) -> CaCl2(aq) +H2(g) ↑ + heat
The clues that it is a chemical reaction could be:
- formation of a new substance, gaseous hydrogen
- disappearance of a metallic solid in the solution
- heat formed during the vigorous reaction.
As silver is below hydrogen in the electrochemical series, it will not be expected to react with dilute hydrocloric acid. (however, it dissolves in oxidizing acid such as nitric acid, but not displacing hydrogen as a product).