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ahrayia [7]
3 years ago
5

Which of the following reactions could be used to extract the lead from the lead nitrate?

Chemistry
1 answer:
alexgriva [62]3 years ago
4 0

Answer:

Option b. Decomposition

Followed by a reduction process using charcoal

Explanation:

Lead can be obtained from lead nitrate by thermal decomposition of lead nitrate as shown below:

2Pb(NO3)2 —> 2PbO + 4NO2 + O2

The PbO obtained is reduced by charcoal(C) to obtain the metallic Pb as shown below:

2PbO + C —> Pb + CO2

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Answer : The value of \Delta H_{vap} is 28.97 kJ/mol

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To calculate \Delta H_{vap} of the reaction, we use clausius claypron equation, which is:

\ln(\frac{P_2}{P_1})=\frac{\Delta H_{vap}}{R}[\frac{1}{T_1}-\frac{1}{T_2}]

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P_1 = vapor pressure at temperature -21.0^oC = 462.7 mmHg

P_2 = vapor pressure at temperature -44.0^oC = 140.5 mmHg

\Delta H_{vap} = Enthalpy of vaporization = ?

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T_1 = initial temperature = -21.0^oC=[-21.0+273]K=252K

T_2 = final temperature = 45^oC=[-41.0+273]K=232K

Putting values in above equation, we get:

\ln(\frac{140.5mmHg}{462.7mmHg})=\frac{\Delta H_{vap}}{8.314J/mol.K}[\frac{1}{252}-\frac{1}{232}]\\\\\Delta H_{vap}=28966.6J/mol=28.97kJ/mol

Therefore, the value of \Delta H_{vap} is 28.97 kJ/mol

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