In the contact process, sulfuric acid is manufactured by first oxidizing SO2 to SO3, which is then reacted with water. The react
ion of SO2 with O2 is
2SO2(g) 1 O2(g) m 2SO3(g)
A 2.000-L flask was filled with 0.0400 mol SO2 and 0.0200 mol O2. At equilibrium at 900 K, the flask contained 0.0296 mol SO3. How many moles of each substance were in the flask at equilibrium?
2SO2(g) 1 O2(g) m 2SO3(g)
A 2.000-L flask was filled with 0.0400 mol SO2 and 0.0200 mol O2. At equilibrium at 900 K, the flask contained 0.0296 mol SO3. How many moles of each substance were in the flask at equilibrium?
1 answer:
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Answer:
The new temperature of the nitrogen gas is 516.8 K or 243.8 C.
Explanation:
Gay-Lussac's law indicates that, as long as the volume of the container containing the gas is constant, as the temperature increases, the gas molecules move faster. Then the number of collisions with the walls increases, that is, the pressure increases. That is, the pressure of the gas is directly proportional to its temperature.
Gay-Lussac's law can be expressed mathematically as follows:
Where P = pressure, T = temperature, K = Constant
You want to study two different states, an initial state and a final state. You have a gas that is at a pressure P1 and at a temperature T1 at the beginning of the experiment. By varying the temperature to a new value T2, then the pressure will change to P2, and the following will be fulfilled:
In this case:
- P1= 2 atm
- T1= 50 C= 323 K (being 0 C= 273 K)
- P2= 3.2 atm
- T2= ?
Replacing:
Solving:
T2= 516.8 K= 243.8 C
<u><em>The new temperature of the nitrogen gas is 516.8 K or 243.8 C.</em></u>
The question is incomplete. Complete question is attached below
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Correct Answer: Option C i.e. I ~ III < IV < V < II
Reason:
During a nucleophilic subsitution reaction of chloroarenes, Cl- group is replaced by an nucleophile like OH-.
Order of reactivity, during such reactions depends on the electron density on carbon atom that is attached to Cl. Lower the electron density, greater will be the reactivity.
Among the provided chloroarenes, electron density on C atom will be minimum in case of compound II, because of presence of electron withdrawing group (-NO2) at ortho and para position. Due to this, there will be large number of resonating structures. This signifies greater electron de-localization, and hence largest reactivity for nucleophilic substitution reaction.
Followed by this, compound V will show greater reactivity, due to presence of -NO2 group at para and one of the ortho position. Compound IV will have less number of resonating structures as compared to compound II and V, hence it will display poor reactivity towards nucleophilic substitution reaction.
Finally, compound 1 and III will minimum reactivity towards nucleophilic substitution reaction, because -NO2 group present at meta position (compound III) will not participate in resonance.
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Correct Answer: Option C i.e. I ~ III < IV < V < II
Reason:
During a nucleophilic subsitution reaction of chloroarenes, Cl- group is replaced by an nucleophile like OH-.
Order of reactivity, during such reactions depends on the electron density on carbon atom that is attached to Cl. Lower the electron density, greater will be the reactivity.
Among the provided chloroarenes, electron density on C atom will be minimum in case of compound II, because of presence of electron withdrawing group (-NO2) at ortho and para position. Due to this, there will be large number of resonating structures. This signifies greater electron de-localization, and hence largest reactivity for nucleophilic substitution reaction.
Followed by this, compound V will show greater reactivity, due to presence of -NO2 group at para and one of the ortho position. Compound IV will have less number of resonating structures as compared to compound II and V, hence it will display poor reactivity towards nucleophilic substitution reaction.
Finally, compound 1 and III will minimum reactivity towards nucleophilic substitution reaction, because -NO2 group present at meta position (compound III) will not participate in resonance.