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In-s [12.5K]
3 years ago
10

Complete the following single replacement reaction. If they don’t react, just write “NR”

Chemistry
1 answer:
Kipish [7]3 years ago
4 0

Here we have to complete the given single replacement reactions.

The replacement reactions are-

1) Fe (s) + CuCl₂ (aq) → FeCl₂ (aq) + Cu (s)

2) Cu (s) + FeCl₂ (aq) → NA

3) K (s) + NiBr₂ (aq) → NA

4) Ni (s) + KBr (aq) → NiBr₂ (aq) + K (s)

5) Zn (s) + Ca(NO₃)₂ (aq) → Zn(NO₃)₂ (aq)  + Ca (s)

6) Ca (s) + Zn(NO₃)₂ (aq) → NA

The replacement reactions can be explained in light of the redox potential.

The standard reduction potential of the half cells involved in these reactions are:

Fe²⁺ + 2e → Fe (E° = -0.441V); Cu²⁺ + 2e → Cu (E° = 0.674V)

Ni²⁺ + 2e → Ni (E° = -0.23V); Zn²⁺ + 2e → Zn (E° = -0.763V)

We know the half cell reactions in which the standard reduction potentials are positive are allowed.

1) The reaction is possible as Cu²⁺/Cu and Fe/Fe²⁺ standard reduction potentials are positive.

2) The reaction is not possible as Cu/Cu²⁺ and Fe²⁺/Fe standard reduction potentials are negative.

3) The reaction is not possible as Ni²⁺/Ni standard reduction potential is negative.

4) The reaction is possible as Ni/Ni²⁺ standard reduction potential is positive.

5) The reaction is possible as Zn/Zn²⁺ standard reduction potential is positive.

6) The reaction is possible as Zn²⁺/Zn standard reduction potential is negative.

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Answer:

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A 15.0 ml sample of gas at 10.0 degree Celsius and 760 torr changes to a pressure of 1252 torr at 35.0 degree Celsius. What is t
netineya [11]

Answer:

9.91 mL

Explanation:

Using the combined gas law equation as follows;

P1V1/T1 = P2V2/T2

Where;

P1 = initial pressure (torr)

P2 = final pressure (torr)

V1 = initial volume (mL)

V2 = final volume (mL)

T1 = initial temperature (K)

T2 = final temperature (K)

According to the information provided in this question;

V1 = 15.0mL

V2 = ?

P1 = 760 torr

P2 = 1252 torr

T1 = 10°C = 10 + 273 = 283K

T2 = 35°C = 35 + 273 = 308K

Using P1V1/T1 = P2V2/T2

760 × 15/283 = 1252 × V2/308

11400/283 = 1252V2/308

Cross multiply

11400 × 308 = 283 × 1252V2

3511200 = 354316V2

V2 = 3511200 ÷ 354316

V2 = 9.91 mL

4 0
3 years ago
A small container of perfume is opened in a classroom. Soon every student in the room smells the perfume. Explain this in terms
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Answer: possibly diffusion

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all particles are in motion unless at a certain degree so they'd spread throughout the room diluting as they continue to spread out.

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Why would you use a solution, such as a cabbage pH indicator, to measure the pH of household items? to see if food went bad to t
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(i) Based on the graph, determine the order of the decomposition reaction of cyclobutane at 1270 K. Justify your answer.
Leni [432]

Answer:

(c)(i) The order of the reaction based on the graph provided is first order.

(ii) 99% of the cyclobutane would have decomposed in 53.15 milliseconds.

d) Rate = K [Cl₂]

K = rate constant

The justification is presented in the Explanation provided below.

e) A catalyst is a substance that alters the rate of a reaction without participating or being used up in the reaction.

Cl₂ is one of the reactants in the reaction, hence, it participates actively and is used up in the process of the reaction, hence, it cannot be termed as a catalyst for the reaction.

So, this shows why the student's claim is false.

Explanation:

To investigate the order of a reaction, a method of trial and error is usually employed as the general equations for the amount of reactant left for various orders are known.

So, the behaviour of the plot of maybe the concentration of reactant with time, or the plot of the natural logarithm of the concentration of reactant with time.

The graph given is evidently an exponential function. It is a graph of the concentration of cyclobutane declining exponentially with time. This aligns with the gemeral expression of the concentration of reactants for a first order reaction.

C(t) = C₀ e⁻ᵏᵗ

where C(t) = concentration of the reactant at any time

C₀ = Initial concentration of cyclobutane = 1.60 mol/L

k = rate constant

The rate constant for a first order reaction is given

k = (In 2)/T

where T = half life of the reaction. It is the time taken for the concentration of the reactant to fall to half of its initial concentration.

From the graph, when the concentration of reactant reaches half of its initial concentration, that is, when C(t) = 0.80 mol/L, time = 8.0 milliseconds = 0.008 s

k = (In 2)/0.008 = (0.693/0.008) = 86.64 /s

(ii) Calculate the time, in milliseconds, that it would take for 99 percent of the original cyclobutane at 1270 K to decompose

C(t) = C₀ e⁻ᵏᵗ

when 99% of the cyclobutane has decomposed, there's only 1% left

C(t) = 0.01C₀

k = 86.64 /s

t = ?

0.01C₀ = C₀ e⁻ᵏᵗ

e⁻ᵏᵗ = 0.01

In e⁻ᵏᵗ = In 0.01 = -4.605

-kt = -4.605

t = (4.605/k) = (4.605/86.64) = 0.05315 s = 53.15 milliseconds.

d) The reaction mechanism for the reaction of cyclopentane and chlorine gas is given as

Cl₂ → 2Cl (slow)

Cl + C₅H₁₀ → HCl + C₅H₉ (fast)

C₅H₉ + Cl → C₅H₉Cl (fast)

The rate law for a reaction is obtained from the slow step amongst the the elementary reactions or reaction mechanism for the reaction. After writing the rate law from the slow step, any intermediates that appear in the rate law is then substituted for, using the other reaction steps.

For This reaction, the slow step is the first elementary reaction where Chlorine gas dissociates into 2 Chlorine atoms. Hence, the rate law is

Rate = K [Cl₂]

K = rate constant

Since, no intermediates appear in this rate law, no further simplification is necessary.

The obtained rate law indicates that the reaction is first order with respect to the concentration of the Chlorine gas and zero order with respect to cyclopentane.

e) A catalyst is a substance that alters the rate of a reaction without participating or being used up in the reaction.

Cl₂ is one of the reactants in the reaction, hence, it participates actively and is used up in the process of the reaction, hence, it cannot be termed as a catalyst for the reaction.

So, this shows why the student's claim is false.

Hope this Helps!!!

6 0
3 years ago
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