Answer:
Option (d) is correct
N³⁻ > F⁻ > Mg²⁺ > Si⁴⁺
Explanation:
Total electrons for all the species = 10
So these are <u>iso electronic</u> with each other.
We know
Ionic radii ∝ 
- Si⁴⁺ has 14 protons and 10 electrons
- Mg²⁺ has 12 protons and 10 electrons
- N³⁻ has 7 protons and 10 electrons
- F⁻ has 9 protons and 10 electrons
- Iso electronic species with greatest number of protons have small size and vice versa.
- So Si⁺⁴ have smallest size and N³⁻ have largest in size
To solve the problem, we assume the sample to be ideal. Then, we use the ideal gas equation which is expressed as PV = nRT. From the first condition of the nitrogen gas sample, we calculate the number of moles.
n = PV / RT
n = (98.7x 10^3 Pa x 0.01 m^3) / (8.314 Pa m^3/ mol K) x 298.15 K
n = 0.40 mol N2
At the second condition, the number of moles stays the same however pressure and temperature was changed. So, the new volume is calculated as follows:
V = nRT / P
V = 0.40 x 8.314 x 293.15 / 102.7 x 10^3
V = 9.49 x 10^-3 m^3 or 9.49 L
Total = <span>products + reactants</span>