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Otrada [13]
3 years ago
15

Your task is to create a buffered solution. You are provided with 0.10 M solutions of formic acid and sodium formate. Formic aci

d has a pKa of 3.75. 2. Create approximately 20 mL of buffer solution with a pH of 4.25.
Chemistry
1 answer:
Anton [14]3 years ago
4 0

Answer:

15.2mL of the 0.10M sodium formate solution and 4.8mL of the 0.10M formic acid solution.

Explanation:

To find the pH of a buffer based on the concentration of the acid and conjugate base we must use Henderson-Hasselbalch equation:

pH = pKa + log [A⁻] / [HA]

<em>Where [A⁻] could be taken as moles of the sodium formate and [HA] moles of the formic acid</em>

<em />

4.25 = 3.75 + log [A⁻] / [HA]

0.5 = log [A⁻] / [HA]

3.162 = [A⁻] / [HA] <em>(1)</em>

<em></em>

As both solutions are 0.10M and you want to create 20mL of the buffer, the moles are:

0.10M  * 20x10⁻³L =

2x10⁻³moles = [A⁻] + [HA] <em>(2)</em>

Replacing (2) in (1):

3.162 = 2x10⁻³moles - [HA] / [HA]

3.162 [HA] = 2x10⁻³moles - [HA]

4.162[HA] = 2x10⁻³moles

[HA] = 4.805x10⁻⁴ moles

[A⁻] = 2x10⁻³moles - 4.805x10⁻⁴ moles = 1.5195x10⁻³moles

That means, to create the buffer you must add:

[A⁻] = 1.5195x10⁻³moles * (1L / 0.10mol) = 0.0152L =

<h3>15.2mL of the 0.10M sodium formate solution</h3>

[HA] = 4.805x10⁻⁴ moles * (1L / 0.10mol) = 0.0048L =

<h3>4.8mL of the 0.10M formic acid solution</h3>
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