Following are the possible isomers of secondary alcohol and ketones for six carbon molecules. In order to distinguish between sec. alcohol and ketone we can simply treat the unknown compound with acidified Potassium Dichromate (VI) in the presence of acid. If with treatment with unknown compound the colour of K2Cr2O7 (potassium dichromate VI) changes from orange to green then it is confirmed that the unknown compound is sec. alcohol, or if no change in colour is detected then ketone is confirmed. This is because ketone can not be further oxidized while, sec. alcohol can be oxidized to ketones as shown below,
Answer:
202 L
Explanation:
Step 1: Write the balanced equation
C₆H₁₂O₆ + 6 O₂(g) ⇒ 6 CO₂(g) + 6 H₂O(l)
Step 2: Calculate the moles corresponding to 270 g of C₆H₁₂O₆
The molar mass of C₆H₁₂O₆ is 180.16 g/mol.
270 g × 1 mol/180.16 g = 1.50 mol
Step 3: Calculate the moles of CO₂ generated from 1.50 moles of glucose
The molar ratio of C₆H₁₂O₆ to CO₂ is 1:6. The moles of CO₂ formed are 6/1 × 1.50 mol = 9.00 mol
Step 4: Calculate the volume of 9.00 moles of CO₂ at STP
The volume of 1 mole of an ideal gas at STP is 22.4 L.
9.00 mol × 22.4 L/mol = 202 L
Nonpolar compound would be symmetrical