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Katyanochek1 [597]
3 years ago
8

Calculate the enthalpy for this reaction: 2C(s) + H2(g) ---> C2H2(g) ΔH° = ??? kJ Given the following thermochemical equation

s: C2H2(g) + (5/2)O2(g) ---> 2CO2(g) + H2O(ℓ) ΔH° = -1,123 kJ C(s) + O2(g) ---> CO2(g) ΔH° = -340 kJ H2(g) + (1/2)O2(g) ---> H2O(ℓ) ΔH° = -211 kJ
Chemistry
1 answer:
nordsb [41]3 years ago
5 0

Answer:

The enthalpy for given reaction is 232 kilo Joules.

Explanation:

C_2H_2(g) + \frac{5}{2}O_2(g)\rightarrow 2CO_2(g) + H_2O(l), \Delta H^o_{1} = -1,123 kJ...[1]

C(s) + O_2(g)\rightarrow CO2(g), \Delta H^o_{2} = -340 kJ..[2]

H_2(g) + \frac{1}{2}O_2(g)\rightarrow H_2O(l) ,\Delta H^o_{3} = -211 kJ..[3]

2C(s) + H_2(g)\rightarrow C_2H_2(g),\Delta H^o_{4} =?..[4]

2 × [2] + [3] - [1] ( Using Hess's law)

\Delta H^o_{4}=2\times \Delta H^o_{2}+\Delta H^o_{3} - \Delta H^o_{1}

\Delta H^o_{4}=2\times (-340 kJ) + (-211 kJ) - (-1,123 kJ)

\Delta H^o_{4}=232 kJ

The enthalpy for given reaction is 232 kilo Joules.

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levacccp [35]

The given question is incomplete. The complete question is as follows.

Sodium sulfate is slowly added to a solution containing 0.0500 M Ca^{2+}(aq) and 0.0390 M Ag^{+}(aq). What will be the concentration of Ca^{2+}(aq) when Ag_{2}SO_{4}(s) begins to precipitate? What percentage of the Ca^{2+}(aq) can be separated from the Ag(aq) by selective precipitation?

Explanation:

The given reaction is as follows.

      Ag_{2}SO_{4} \rightleftharpoons 2Ag^{+} + SO^{2-}_{4}

[Ag^{+}] = 0.0390 M

When Ag_{2}SO_{4} precipitates then expression for K_{sp} will be as follows.

         K_{sp} = [Ag^{+}]^{2}[SO^{2-}_{4}]

        1.20 \times 10^{-5} = (0.0390)^{2} \times [SO^{2-}_{4}]

       [SO^{2-}_{4}] = 0.00788 M

Now, equation for dissociation of calcium sulfate is as follows.

         CaSO_{4} \rightleftharpoons Ca^{2+} + SO^{2-}_{4}

      K_{sp} = [Ca^{2+}][SO^{2-}_{4}]

     4.93 \times 10^{-5} = [Ca^{2+}] \times 0.00788

           [Ca^{2+}] = 0.00625 M

Now, we will calculate the percentage of Ca^{2+} remaining in the solution as follows.

               \frac{0.00625}{0.05} \times 100

                 = 12.5%

And, the percentage of Ca^{2+} that can be separated is as follows.

                     100 - 12.5

                     = 87.5%

Thus, we can conclude that 87.5% will be the concentration of Ca^{2+}(aq) when Ag_{2}SO_{4}(s) begins to precipitate.

4 0
3 years ago
Complete combustion of 3.20g of a hydrocarbon produced 9.69g of CO2 and 4.96g of H2O. What is the empirical formula for the hydr
vlabodo [156]

Let empirical formula for hydrocarbon is CxHy

it will undergo combustion as

CxHy + (x + y/4) O2  ---> xCO2 + (y/2 )H2O

Given that mass of CO2 produced = 9.69 g

So moles of CO2 produced = 9.69 / 44 = 0.22 moles

So moles of carbon present = 0.22 moles

mass of H2O produced = 4.96 g

Moles of H2O produced = mass / molar mass = 4.96 / 18 = 0.28 moles

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Multiplying with two to get whole number

the ratio of carbon and hydrogen will be : C:H = 2:5

empirical formula : C2H5


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