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slavikrds [6]
3 years ago
14

You are given a solution of HCOOH (formic acid) with an approximate concentration of 0.20 M and you will titrate this with a 0.1

105 M NaOH. If you add 20.00 mL of HCOOH to the beaker before titrating, approximately what volume of NaOH will be required to reach the end point? View Available Hint(s) You are given a solution of (formic acid) with an approximate concentration of 0.20 and you will titrate this with a 0.1105 . If you add 20.00 of to the beaker before titrating, approximately what volume of will be required to reach the end point? 11.1 mL 20.0 mL 72.4 mL 36.2 mL
Chemistry
1 answer:
jeka57 [31]3 years ago
3 0

Answer:

\boxed{\text{36 mL}}

Explanation:

1. Write the balanced chemical equation.

\rm HCOOH + NaOH $ \longrightarrow$ HCOONa + H$_{2}$O

2. Calculate the moles of HCOOH

\text{Moles of HCOOH} =\text{20.00 mL HCOOH } \times \dfrac{\text{0.20 mmol HCOOHl}}{\text{1 mL HCOOH}} = \text{4.00 mmol HCOOH}

3. Calculate the moles of NaOH.

\text{Moles of NaOH = 4.00 mmol HCOOH } \times \dfrac{\text{1 mmol NaOH} }{\text{1 mmol HCOOH}} = \text{4.00 mmol NaOH}

4. Calculate the volume of NaOH

c = \text{4.00 mmol NaOH } \times \dfrac{\text{1 mL NaOH }}{\text{0.1105 mmol NaOH }} = \textbf{36 mL NaOH }\\\\\text{The titration will require }\boxed{\textbf{36 mL of NaOH}}

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Ethanol (C2H5OH) melts a - 144 oC and boils at 78 °C. The enthalpy of fusion of ethanol is 5.02 kj/mol, and its enthalpy of vapo
Romashka [77]

<u>Answer:</u>

<u>For a:</u> The total heat required is 36621.5 J

<u>For b:</u> The total heat required is 58944.5 J

<u>Explanation:</u>

  • <u>For a:</u>

To calculate the heat required at different temperature, we use the equation:

q=mc\Delta T         .........(1)

where,

q = heat absorbed

m = mass of substance

c = specific heat capacity of substance

\Delta T = change in temperature

To calculate the amount of heat required at same temperature, we use the equation:

q=m\times \Delta H      ........(2)

where,

q = heat absorbed

m = mass of substance

\Delta H = enthalpy of the reaction

The processes involved in the given problem are:

1.)C_2H_5OH(l)(35^oC)\rightarrow C_2H_5OH(l)(78^oC)\\2.)C_2H_5OH(l)(78^oC)\rightarrow C_2H_5OH(g)(78^oC)

  • <u>For process 1:</u>

We are given:

Change in temperature remains the same.

m=42.0g\\c_l=2.3J/g.K\\T_2=78^oC\\T_1=35^oC\\\Delta T=[T_2-T_1]=[78-35]^oC=43^oC=43K

Putting values in equation 1, we get:

q_1=42.0g\times 2.3J/g.K\times 43K\\\\q_1=4153.8J

  • <u>For process 2:</u>

We are given:

Conversion factor: 1 kJ = 1000 J

Molar mass of ethanol = 46 g/mol

m=42.0g\\\Delta H_{vap}=38.56kJ/mol=\frac{35.56kJ}{1mol}\times (\frac{1000J}{1kJ})\times (\frac{1}{46g/mol})=773.04J/g

Putting values in equation 2, we get:

q_2=42.0g\times 773.04J/g\\\\q_2=32467.7J

Total heat required = [q_1+q_2]

Total heat required = [4153.8J+32467.7J]=36621.5J

Hence, the total heat required is 36621.5 J

  • <u>For b:</u>

The processes involved in the given problem are:  

1.)C_2H_5OH(s)(-155^oC)\rightarrow C_2H_5OH(s)(-144^oC)\\2.)C_2H_5OH(s)(-144^oC)\rightarrow C_2H_5OH(l)(-144^oC)\\3.)C_2H_5OH(l)(-144^oC)\rightarrow C_2H_5OH(l)(78^oC)\\4.)C_2H_5OH(l)(78^oC)\rightarrow C_2H_5OH(g)(78^oC)

  • <u>For process 1:</u>

We are given:

Change in temperature remains the same.

m=42.0g\\c_s=0.97J/g.K\\T_2=-144^oC\\T_1=-155^oC\\\Delta T=[T_2-T_1]=[-144-(-155)]^oC=11^oC=11K

Putting values in equation 1, we get:

q_1=42.0g\times 0.97J/g.K\times 11K\\\\q_1=448.14J

  • <u>For process 2:</u>

We are given:

m=42.0g\\\Delta H_{fusion}=5.02kJ/mol=\frac{5.02kJ}{1mol}\times (\frac{1000J}{1kJ})\times (\frac{1}{46g/mol})=109.13J/g

Putting values in equation 2, we get:

q_2=42.0g\times 109.13J/g\\\\q_2=4583.5J

  • <u>For process 3:</u>

We are given:

Change in temperature remains the same.

m=42.0g\\c_l=2.3J/g.K\\T_2=78^oC\\T_1=-144^oC\\\Delta T=[T_2-T_1]=[78-(-144)]^oC=222^oC=222K

Putting values in equation 1, we get:

q_3=42.0g\times 2.3J/g.K\times 222K\\\\q_3=21445.2J

  • <u>For process 4:</u>

We are given:

m=42.0g\\\Delta H_{vap}=38.56kJ/mol=\frac{38.56kJ}{1mol}\times (\frac{1000J}{1kJ})\times (\frac{1}{46g/mol})=773.04J/g

Putting values in equation 2, we get:

q_4=42.0g\times 773.04J/g\\\\q_4=32467.7J

Total heat required = [q_1+q_2+q_3+q_4]

Total heat required = [448.14+4583.5+21445.2+32467.7]J=58944.5J

Hence, the total heat required is 58944.5 J

7 0
3 years ago
Which one is it answer the question
Assoli18 [71]

Answer:

Both are only physical changes.

Explanation:

Nothing about the objects chemically change, and they remain the same.

Their changes arent due to heating/cooling.

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Answer:

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irga5000 [103]

10 core elections

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 A substance has 55.80% carbon, 7.04% Hydrogen, and 37.16% Oxygen. What is it's empirical and molecular formula if it has a mola
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55.80 C/12= 4.65/2.3225= 2

7.04 H/1= 7.04/2.3225= 3

37.16 O/16= 2.3225/2.3225= 1

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