A low specific heat capacity
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Answer:
See explanation
Explanation:
All molecules possess the London dispersion forces. However London dispersion forces is the only kind of intermolecular interaction that exists in nonpolar substances.
So, the only kind of intermolecular interaction that exists in dimethyl ether is London dispersion forces.
As for ethyl alcohol, the molecule is polar due to the presence of polar O-H bond. In addition to London dispersion forces, dipole-dipole interactions and specifically hydrogen bonding also occurs between the molecules.
Because ethyl alcohol is polar, it is more soluble in water than dimethyl ether.
<u>Answer:</u> The value of
of the reaction is 28.38 kJ/mol
<u>Explanation:</u>
For the given chemical reaction:

- The equation used to calculate enthalpy change is of a reaction is:
![\Delta H^o_{rxn}=\sum [n\times \Delta H^o_f_{(product)}]-\sum [n\times \Delta H^o_f_{(reactant)}]](https://tex.z-dn.net/?f=%5CDelta%20H%5Eo_%7Brxn%7D%3D%5Csum%20%5Bn%5Ctimes%20%5CDelta%20H%5Eo_f_%7B%28product%29%7D%5D-%5Csum%20%5Bn%5Ctimes%20%5CDelta%20H%5Eo_f_%7B%28reactant%29%7D%5D)
The equation for the enthalpy change of the above reaction is:
![\Delta H^o_{rxn}=[(1\times \Delta H^o_f_{(SO_2Cl_2(g))})]-[(1\times \Delta H^o_f_{(SO_2(g))})+(1\times \Delta H^o_f_{(Cl_2(g))})]](https://tex.z-dn.net/?f=%5CDelta%20H%5Eo_%7Brxn%7D%3D%5B%281%5Ctimes%20%5CDelta%20H%5Eo_f_%7B%28SO_2Cl_2%28g%29%29%7D%29%5D-%5B%281%5Ctimes%20%5CDelta%20H%5Eo_f_%7B%28SO_2%28g%29%29%7D%29%2B%281%5Ctimes%20%5CDelta%20H%5Eo_f_%7B%28Cl_2%28g%29%29%7D%29%5D)
We are given:

Putting values in above equation, we get:
![\Delta H^o_{rxn}=[(1\times (-364))]-[(1\times (-296.8))+(1\times 0)]=-67.2kJ/mol=-67200J/mol](https://tex.z-dn.net/?f=%5CDelta%20H%5Eo_%7Brxn%7D%3D%5B%281%5Ctimes%20%28-364%29%29%5D-%5B%281%5Ctimes%20%28-296.8%29%29%2B%281%5Ctimes%200%29%5D%3D-67.2kJ%2Fmol%3D-67200J%2Fmol)
- The equation used to calculate entropy change is of a reaction is:
![\Delta S^o_{rxn}=\sum [n\times \Delta S^o_f_{(product)}]-\sum [n\times \Delta S^o_f_{(reactant)}]](https://tex.z-dn.net/?f=%5CDelta%20S%5Eo_%7Brxn%7D%3D%5Csum%20%5Bn%5Ctimes%20%5CDelta%20S%5Eo_f_%7B%28product%29%7D%5D-%5Csum%20%5Bn%5Ctimes%20%5CDelta%20S%5Eo_f_%7B%28reactant%29%7D%5D)
The equation for the entropy change of the above reaction is:
![\Delta S^o_{rxn}=[(1\times \Delta S^o_{(SO_2Cl_2(g))})]-[(1\times \Delta S^o_{(SO_2(g))})+(1\times \Delta S^o_{(Cl_2(g))})]](https://tex.z-dn.net/?f=%5CDelta%20S%5Eo_%7Brxn%7D%3D%5B%281%5Ctimes%20%5CDelta%20S%5Eo_%7B%28SO_2Cl_2%28g%29%29%7D%29%5D-%5B%281%5Ctimes%20%5CDelta%20S%5Eo_%7B%28SO_2%28g%29%29%7D%29%2B%281%5Ctimes%20%5CDelta%20S%5Eo_%7B%28Cl_2%28g%29%29%7D%29%5D)
We are given:

Putting values in above equation, we get:
![\Delta S^o_{rxn}=[(1\times 311.9)]-[(1\times 248.2)+(1\times 223.0)]=-159.3J/Kmol](https://tex.z-dn.net/?f=%5CDelta%20S%5Eo_%7Brxn%7D%3D%5B%281%5Ctimes%20311.9%29%5D-%5B%281%5Ctimes%20248.2%29%2B%281%5Ctimes%20223.0%29%5D%3D-159.3J%2FKmol)
To calculate the standard Gibbs's free energy of the reaction, we use the equation:

where,
= standard enthalpy change of the reaction =-67200 J/mol
= standard entropy change of the reaction =-159.3 J/Kmol
Temperature of the reaction = 600 K
Putting values in above equation, we get:

Hence, the value of
of the reaction is 28.38 kJ/mol
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