The mass percentage of hydrochloric acid within a solution is 15.00%. given that the density of this solution is 1.075 g/ml, fin
1 answer:
Given the mass percentage of HCl solution = 15.00 %
This means that 15.00 g HCl is present in 100 g solution
Moles of HCl =
Density of the solution = 1.075 g/mL
Calculating the volume of solution from density and mass:
Converting volume from mL to L:
Calculating the molarity of HCl solution from moles and volume:
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The molarity of formic acid is 100 mM or . The dissociation reaction of formic acid is as follows:
The expression for dissociation constant of the reaction will be:
Rearranging,
Here, pH of solution is 4.15 thus, concentration of hydrogen ion will be:
Similarly, thus,
Putting the values,
Therefore, the concentration of formate will be 0.2511 M.
Answer:
High activation energy is the reason behind unsuccessful reaction.
Explanation:
There are two types of reaction: (1) thermodynamically controlled reaction and (2) kinetically controlled reaction.
Thermodynamically controlled reaction are associated with change in enthalpy during reaction. More negative the enthalpy change, more favored will be the reaction.
Kinetically controlled reaction are associated with activation energy of a reaction. The lower the activation energy value, the more rapid will be the reaction.
Here, reaction between and
is thermodynamically favored due to negative enthalpy change but the high activation energy does not allow the reaction to take place by simple mixing.