Answer:
(A) Work done will be 87.992 KJ
(B) Work done will be 167.4 KJ
Explanation:
We have given mass of methane m = 4.5 gram = 0.0045 kg
Volume occupies 
And volume is increased by
so 
Temperature T = 310 K
Pressure is given as 200 Torr = 26664.5 Pa
(a) At constant pressure work done is given by

(b) At reversible process work done is given by 
We have given mass = 4.5 gram
Molar mass of methane = 16
So number of moles 
So work done 