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Ad libitum [116K]
2 years ago
15

A solution containing a mixture of 0.0333 M0.0333 M potassium chromate ( K2CrO4K2CrO4 ) and 0.0532 M0.0532 M sodium oxalate ( Na

2C2O4Na2C2O4 ) was titrated with a solution of barium chloride ( BaCl2BaCl2 ) for the purpose of separating CrO2−4CrO42− and C2O2−4C2O42− by precipitation with the Ba2+Ba2+ cation. The solubility product constants ( KspKsp ) for BaCrO4BaCrO4 and BaC2O4BaC2O4 are 2.10×10−102.10×10−10 and 1.30×10−61.30×10−6 , respectively.
A) Which barium salt will precipitate first? O BaC204 O BaCrO4
B) What concentration of Ba2+ must be present for BaCrO4 to begin precipitating? Number [Ba2+]=
C) What concentration of Ba is required to reduce oxalate to 10% of its original concentration? Number 2+
D) What is the ratio of oxalate to chromate (IC204CrO4) when the Ba2 concentration is 0.0050 M? Number C,O Cro,
Chemistry
1 answer:
jasenka [17]2 years ago
3 0

Answer:

Explanation:

K₂CrO₄ + ( COONa )₂ + 2BaCl₂ = Ba CrO₄ + ( COO ) ₂ Ba + 2 KCl + 2 NaCl

.033 M             .053 M    

Ksp of   Ba CrO₄  is      2.10×10⁻¹⁰

Ksp of ( COO ) ₂ Ba  is   1.30×10⁻⁶

A ) Ksp of   Ba CrO₄ is less so it will precipitate out first .

B) Ksp = 2.10×10⁻¹⁰

Ba CrO₄ = Ba⁺²  +  CrO₄⁻²

                   C            .033

C x   .033  = 2.10×10⁻¹⁰

C =  63.63 x 10⁻¹⁰ M

Ba⁺² must be present in concentration = 63.63 x 10⁻¹⁰ M

C)

90% of precipitation of barium oxalate

concentration of oxalate to precipitate out = .9 x .0532 = .04788

( COO ) ₂ Ba  =  (COO)₂⁻²     +       Ba⁺²

                           .04788 M            C  

C x  .04788  =  1.30×10⁻⁶

C = 27.15  x 10⁻⁶ M .

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A cyanide solution with avolume of 12.73 mL was treated with 25.00 mL of Ni2+solution (containing
natima [27]

Answer:

The molarity of this solution is 0,09254M

Explanation:

The concentration of the Ni²⁺ solution is:

Ni²⁺ + EDTA⁴⁻ → Ni(EDTA)²⁻

0,03935L × 0,01307M = 5,143x10⁻⁴ moles Ni²⁺ ÷ 0,03010L =<em>0,01709M Ni²⁺</em>

25,00 mL of this solution contain:

0,01709M × 0,02500L = 4,2716x10⁻⁴ moles of Ni²⁺

The moles of Ni²⁺ that are in excess and react with EDTA⁴⁻ are:

0,01015L × 0,01307M = 1,3266x10⁻⁴ moles of Ni²⁺

Thus, moles of Ni²⁺ that react with CN⁻ are:

4,2716x10⁻⁴ - 1,3266x10⁻⁴ = 2,9450x10⁻⁴ moles of Ni²⁺

For the reaction:

4CN⁻ + Ni²⁺ → Ni(CN)₄²⁻

Four moles of CN⁻ react with 1 mole of Ni²⁺:

2,9450x10⁻⁴ moles of Ni²⁺ × \frac{4 mol CN^-}{1 molNi^{2+}} = <em>1,178x10⁻³ moles of CN⁻</em>

As the volume of cyanide solution is 12,73mL. The molarity of this solution is:

<em>1,178x10⁻³ moles of CN⁻ ÷ 0,01273L = </em><em>0,09254M</em>

I hope it helps!

5 0
3 years ago
Name the following Type 3 compound
Natasha_Volkova [10]

Answer:

32

Explanation:

5 0
2 years ago
The two methods in the lab for measuring the volume of a geometric solid object are weighing it on the balance and measuring it
Yakvenalex [24]

Answer:

Measuring with a ruler and using final volume minus initial volume

Explanation:

You can measure the volume of a geometric object by measuring its sides with a ruler and calculating the volume according to the corresponding formula for each object. For example, for a rectangular prism it would be

volume=length*width*height

You can also measure the volume of an object by measuring how much water it displaces. To do this you have to fill a measuring cylinder with enough water for the object to be completely submerged and take note of the volume. Then, add the object and note again the volume of the water+object. The difference between both is the volume of the object.

Volume of the object= volume of water and object - volume of water

The advantage of the second method is that it can be used for objects with irregular shapes as long as they do not float.

8 0
3 years ago
A chemical reaction produced 10.1 cm3 of nitrogen gas at 23 °C and 746 mmHg. What is the volume of this gas if the temperature a
adell [148]

Answer:

volume of gas = 9.1436cm³

Explanation:

We will only temperature from °C to K since the conversion is done by the addition of 273 to the Celsius value.

Its not necessary to convert pressure and volume as their conversions are done by multiplication and upon division using the combined gas equation, the factors used in their conversions will cancel out.

V1 =10.1cm³ , P1 =746mmHg,     T1=23°C =23+273=296k

V2 =? ,   P2 =760mmmHg ,     T2=0°C = 0+273 =273K

Using the combined gas equation to calculate for V2;

\frac{V1P1}{T1}=\frac{V2P2}{T2} \\ re-arranging, \\V2 =\frac{V1P1T2}{P2T1}

V2 =\frac{10.1*746*273}{760*296}

V2=9.1436cm³

6 0
3 years ago
Products for combustion<br>​
V125BC [204]

Answer:

Carbon Dioxide

Carbon Monoxide

Sulfur Dioxide

Nitrogen Oxides

Lead

Particulate Matter

Explanation:

7 0
1 year ago
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