The product of reduction of ethyl 4-oxobutanoate with sodium borohydride in ethanol at room temperature for 30 minutes is ethyl 4- hydroxybutanoate .
Sodium borohydride is a relatively selective reducing agent Ethanolic solutions of Sodium borohydride reduces aldehyde , and ketone , in the presence of acid chloride , ester , epoxide , lactones , acids , nitriles , nitro groups.
The sodium borohydride does not reduce ester group because sodium borohydride is not strong enough and the electrophilicity at carbony carbon of ester is not more as compare toaldehyde , and ketone
The product of reduction of ethyl 4-oxobutanoate with sodium borohydride in ethanol at room temperature for 30 minutes is ethyl 4- hydroxybutanoate .
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Answer:
- <u>Alkaline or basic solution </u>(alkaline and basic means the same)
Explanation:
According to the <em>pH</em>, solutions may be classified as neutral, acidic, or alkaline (basic).
This table shows such classification:
pH classification
7 neutral
> 7 alkaline or basic
< 7 acidic
Thus, since the pH of the solution is 8.3, which is greater than 7, the solution is classified as basic (alkaline).
Additionally, you must learn that pH is a logarithmic scale for the concentration of hydronium ions in the solution.
You can calculate the concentration of hydronium ions using antilogarithm properties:
![pH=-log[H_3O^+]\\ \\ {[H_3O^+]}=10^{-pH}\\ \\ {[H_3O^+]}=10^{-8.3}=0.00000000501](https://tex.z-dn.net/?f=pH%3D-log%5BH_3O%5E%2B%5D%5C%5C%20%5C%5C%20%7B%5BH_3O%5E%2B%5D%7D%3D10%5E%7B-pH%7D%5C%5C%20%5C%5C%20%7B%5BH_3O%5E%2B%5D%7D%3D10%5E%7B-8.3%7D%3D0.00000000501)
NaOH solutions are alkaline solutions, bases, according to Arrhenius model, because they contain OH⁻ ions and release them when ionize in water.
The postmortem cooling or algor mortis gets fixed by 8- 10 hours after death. The temperature of the body after death can be used to determine the time since death.