Draw the other possible resonance structure of each organic ion. In each case, draw the structure that minimizes formal charges.
1 answer:
Three resonance structures can be drawn for the allyl cation while two resonance structures can be drawn for the amidate ion.
Sometimes, we cannot fully describe the bonding in a chemical specie using a single chemical structure. In such cases, we have to use a number of structures which cooperatively represent the actual bonding in the molecule. These structures are called resonance or canonical structures.
The resonance structures of the allyl cation and the amidate ion are shown in the images attached to this answer. These structures show the different bonding extremes in these organic ions.
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Explanation :
As we know that the Gibbs free energy is not only function of temperature and pressure but also amount of each substance in the system.
where,
is the amount of component 1 and 2 in the system.
Partial molar Gibbs free energy : The partial derivative of Gibbs free energy with respect to amount of component (i) of a mixture when other variable are kept constant are known as partial molar Gibbs free energy of
component.
For a substance in a mixture, the chemical potential is defined as the partial molar Gibbs free energy.
The expression will be:
where,
T = temperature
P = pressure
is the amount of component 'i' and 'j' in the system.