Answer:
a. 59 m/atm
Explanation:
- To solve this problem, we must mention Henry's law.
- <em>Henry's law states that at a constant temperature, the amount of a given gas dissolved in a given type and volume of liquid is directly proportional to the partial pressure of that gas in equilibrium with that liquid.</em>
- It can be expressed as: C = KP,
C is the concentration of the solution (C = 1.3 M).
P is the partial pressure of the gas above the solution (P = 0.022 atm).
K is the Henry's law constant (K = ??? M/atm),
∵ C = KP.
∴ K = C/P = (1.3 M)/(0.022 atm) = 59.0 M/atm.
Answer:
By adding the solute in to solution boiling point is increased while freezing point is decreased.
Explanation:
When solute in added into the solvent the boiling point of solvent increases for example,
Water is boiled at 100 °C, when sodium chloride is added its boiling point increased. Ions of salt interact with solvent and prevent the water molecules to escape from the surface and form gas molecules. In order to make it boiled solution must be heated above 100 °C.
But there is different case with freezing point. Freezing point is the state in which substance converted into the solid. At given temperature when solute is added into the solvent it prevent the formation of solid. It required time to decrease the temperature first and as the temperature is decreases solid is formed.
First we have to find Ka1 and Ka2
pKa1 = - log Ka1 so Ka1 = 0.059
pKa2 = - log Ka2 so Ka2 = 6.46 x 10⁻⁵
Looking at the values of equilibrium constants we can see that the first one is really big compared to second one. so, the pH will be affected mainly by the first ionization of the acid.
Oxalic acid is H₂C₂O₄
H₂C₂O₄ ⇄ H⁺ + HC₂O₄⁻
0.0356 M 0 0
0.0356 - x x x
Ka1 =
![\frac{[H^+][HC2O4^-]}{[H2C2O4]}](https://tex.z-dn.net/?f=%20%5Cfrac%7B%5BH%5E%2B%5D%5BHC2O4%5E-%5D%7D%7B%5BH2C2O4%5D%7D%20)
= x² / 0.0356 - x
x = 0.025 M
pH = - log [H⁺] = - log (0.025) = 1.6