Answer:
<h3>1)</h3>
Structure One:
Structure Two:
Structure Three:
Structure Number Two would likely be the most stable structure.
<h3>2)</h3>
- All five C atoms: 0
- All six H atoms to C: 0
- N atom: +1.
The N atom is the one that is "likely" to be attracted to an anion. See explanation.
Explanation:
When calculating the formal charge for an atom, the assumption is that electrons in a chemical bond are shared equally between the two bonding atoms. The formula for the formal charge of an atom can be written as:
.
For example, for the N atom in structure one of the first question,
- N is in IUPAC group 15. There are 15 - 10 = 5 valence electrons on N.
- This N atom is connected to only 1 chemical bond.
- There are three pairs, or 6 electrons that aren't in a chemical bond.
The formal charge of this N atom will be 
.
Apply this rule to the other atoms. Note that a double bond counts as two bonds while a triple bond counts as three.
<h3>1)</h3>
Structure One:
Structure Two:
Structure Three:
In general, the formal charge on all atoms in a molecule or an ion shall be as close to zero as possible. That rules out Structure number one.
Additionally, if there is a negative charge on one of the atoms, that atom shall preferably be the most electronegative one in the entire molecule. O is more electronegative than N. Structure two will likely be favored over structure three.
<h3>2)</h3>
Similarly,
- All five C atoms: 0
- All six H atoms to C: 0
- N atom: +1.
Assuming that electrons in a chemical bond are shared equally (which is likely not the case,) the nitrogen atom in this molecule will carry a positive charge. By that assumption, it would attract an anion.
Note that in reality this assumption seldom holds. In this ion, the N-H bond is highly polarized such that the partial positive charge is mostly located on the H atom bonded to the N atom. This example shows how the formal charge assumption might give misleading information. However, for the sake of this particular problem, the N atom is the one that is "likely" to be attracted to an anion.
HA ⇄ H⁺ + A⁻
so:
![\frac{[H^+][A^-]}{[HA]} = 1.5 x 10^{-5}](https://tex.z-dn.net/?f=%20%5Cfrac%7B%5BH%5E%2B%5D%5BA%5E-%5D%7D%7B%5BHA%5D%7D%20%3D%201.5%20x%2010%5E%7B-5%7D%20%20)
and now:
= 1.5 x 10⁻⁵
x is considered very small compared to 0.15
x² = 2.25 x 10⁻⁶
x = 1.5 x 10⁻³
So [H⁺] = 1.5 x 10⁻³
pH = - log [H⁺] = - log (1.5 x 10⁻³) = 2.83
Answer:
The minimum number of boxes of pencils to be ordered is 630 boxes.
Explanation:
Since a pupil uses averagely 9.3 pencils
and a box contains 12 pencils,
the school enrollment is also 812
school's enrollment x average use of pencil per student
__________________________________________
number of pencils in a box
812 x 9.3 = 7551.6
7551.6 /12 = 629.3
Having a total number of 630 boxes of pencils to be ordered.
Factors that determine ionization energy:
- Electronic Repulsion - If the electronic density decreases, the ionization energy with increase and vice versa. If an electron gets released, it decreases the electronic repulsion. This makes releasing another electron harder than the first on unless the electron that is being released comes from another energetic level.
- # Of Energy Levels - The more energy cores that get filled up, the more ionization levels decrease. When we see the energy levels go from top to bottom, the ionization also go from most to least. This is why ionization occurs on the highest level.
- Nuclear Charge - The higher the atomic number, the higher charge in the nuclei. This also makes the ionization energy higher as it increases from left to right of in other words, if the nuclear charge gets higer, the energy gets higher as well.
Factors that determine atomic volume:
- How many protons are in the nucleus (nuclear charge)
- How many energy levels carry electrons (electrons in outer energy level)
Best of Luck!
<u>Answer:</u> The mass of sulfuric acid present in 60 mL of solution is 34.1 grams
<u>Explanation:</u>
We are given:
44 % (m/m) solution of sulfuric acid. This means that 44 grams of sulfuric acid is present in 100 grams of solution.
To calculate volume of a substance, we use the equation:
Density of solution = 1.343 g/mL
Mass of solution = 100 g
Putting values in above equation, we get:
To calculate the mass of sulfuric acid present in 60 mL of solution, we use unitary method:
In 77.46 mL of solution, mass of sulfuric acid present is 44 g
So, in 60 mL of solution, mass of sulfuric acid present will be = 
Hence, the mass of sulfuric acid present in 60 mL of solution is 34.1 grams
