When a substance is heated, it gains thermal energy. Therefore, its particles move faster and its temperature rises. When a substance is cooled, it loses thermal energy, which causes its particles to move more slowly and its temperature to drop.
Answer : The value of
is 28.97 kJ/mol
Explanation :
To calculate
of the reaction, we use clausius claypron equation, which is:
![\ln(\frac{P_2}{P_1})=\frac{\Delta H_{vap}}{R}[\frac{1}{T_1}-\frac{1}{T_2}]](https://tex.z-dn.net/?f=%5Cln%28%5Cfrac%7BP_2%7D%7BP_1%7D%29%3D%5Cfrac%7B%5CDelta%20H_%7Bvap%7D%7D%7BR%7D%5B%5Cfrac%7B1%7D%7BT_1%7D-%5Cfrac%7B1%7D%7BT_2%7D%5D)
where,
= vapor pressure at temperature
= 462.7 mmHg
= vapor pressure at temperature
= 140.5 mmHg
= Enthalpy of vaporization = ?
R = Gas constant = 8.314 J/mol K
= initial temperature = ![-21.0^oC=[-21.0+273]K=252K](https://tex.z-dn.net/?f=-21.0%5EoC%3D%5B-21.0%2B273%5DK%3D252K)
= final temperature = ![45^oC=[-41.0+273]K=232K](https://tex.z-dn.net/?f=45%5EoC%3D%5B-41.0%2B273%5DK%3D232K)
Putting values in above equation, we get:
![\ln(\frac{140.5mmHg}{462.7mmHg})=\frac{\Delta H_{vap}}{8.314J/mol.K}[\frac{1}{252}-\frac{1}{232}]\\\\\Delta H_{vap}=28966.6J/mol=28.97kJ/mol](https://tex.z-dn.net/?f=%5Cln%28%5Cfrac%7B140.5mmHg%7D%7B462.7mmHg%7D%29%3D%5Cfrac%7B%5CDelta%20H_%7Bvap%7D%7D%7B8.314J%2Fmol.K%7D%5B%5Cfrac%7B1%7D%7B252%7D-%5Cfrac%7B1%7D%7B232%7D%5D%5C%5C%5C%5C%5CDelta%20H_%7Bvap%7D%3D28966.6J%2Fmol%3D28.97kJ%2Fmol)
Therefore, the value of
is 28.97 kJ/mol
Answer:
Enthalpy of formation = -947.68KJ/mol
Explanation:
Enthalpy of formation is the heat change when one mole of a substance is formed from its element in its standard states and in standard conditions of temperature and pressure. it may be positive or negative, if positive, it is an endothermic reaction where the heat content of the product is greater than that of the reactants, and if negative, it is exothermic reaction - where the heat content of the reactants is greater than the products. the enthalpy of formation is measured in KiloJoule/Moles (KJ/Mole).
From the value of the enthalpy of formation of NaHCO3, it shows that the reaction is exothermic, that is the formation of NaHCO3 from its constituents elements. As such, the heat content of the reactants is greater than the products.
The step by step explanation is shown in the attachment.
The answer to this would be a physical change. Physical changes are changes that affect the form of a chemical substance, but not the chemical composition itself. Hope this helped!