"Silver chloride is essentially insoluble in water" this statement is true for the equilibrium constant for the dissolution of silver chloride.
Option: b
<u>Explanation</u>:
As silver chloride is essentially insoluble in water but also show sparing solubility, its reason is explained through Fajan's rule. Therefore when AgCl added in water, equilibrium take place between undissolved and dissolved ions. While solubility product constant
for silver chloride is determined by equilibrium concentrations of dissolved ions. But solubility may vary also at different temperatures. Complete solubility is possible in ammonia solution as it form stable complex as water is not good ligand for Ag+.
To calculate
firstly molarity of ions are needed to be found with formula: 
Then at equilibrium cations and anions concentration is considered same hence:
![\left[\mathbf{A} \mathbf{g}^{+}\right]=[\mathbf{C} \mathbf{I}]=\text { molarity of ions }](https://tex.z-dn.net/?f=%5Cleft%5B%5Cmathbf%7BA%7D%20%5Cmathbf%7Bg%7D%5E%7B%2B%7D%5Cright%5D%3D%5B%5Cmathbf%7BC%7D%20%5Cmathbf%7BI%7D%5D%3D%5Ctext%20%7B%20molarity%20of%20ions%20%7D)
Hence from above data
can be calculated by:
= ![\left[\mathbf{A} \mathbf{g}^{+}\right] \cdot[\mathbf{C} \mathbf{I}]](https://tex.z-dn.net/?f=%5Cleft%5B%5Cmathbf%7BA%7D%20%5Cmathbf%7Bg%7D%5E%7B%2B%7D%5Cright%5D%20%5Ccdot%5B%5Cmathbf%7BC%7D%20%5Cmathbf%7BI%7D%5D)
The overall reaction is given by:

The fast step reaction is given as:

The slow step reaction is given as:
(slow step
)
Now, the expression for the rate of reaction of fast reaction is:
![r_{1}=k_{1}[NO][Br_{2}]-k_{-1}[NOBr_{2}]](https://tex.z-dn.net/?f=r_%7B1%7D%3Dk_%7B1%7D%5BNO%5D%5BBr_%7B2%7D%5D-k_%7B-1%7D%5BNOBr_%7B2%7D%5D)
The expression for the rate of reaction of slow reaction is:
Slow step is the rate determining step. Thus, the overall rate of formation is the rate of formation of slow reaction as
takes place in this reaction.
The expression of rate of formation is:

=
(1)
Now, consider that the fast step is always is in equilibrium. Therefore, 
![k_{1}[NO][Br_{2}]= k_{-1}[NOBr_{2}]](https://tex.z-dn.net/?f=k_%7B1%7D%5BNO%5D%5BBr_%7B2%7D%5D%3D%20k_%7B-1%7D%5BNOBr_%7B2%7D%5D)
![[NOBr_{2}] = \frac{k_{1}}{k_{-1}}[NO][Br_{2}]](https://tex.z-dn.net/?f=%5BNOBr_%7B2%7D%5D%20%3D%20%5Cfrac%7Bk_%7B1%7D%7D%7Bk_%7B-1%7D%7D%5BNO%5D%5BBr_%7B2%7D%5D)
Substitute the value of
in equation (1), we get:
![\frac{d(NOBr)}{dt}=k_{2}[NOBr_{2}][NO]](https://tex.z-dn.net/?f=%5Cfrac%7Bd%28NOBr%29%7D%7Bdt%7D%3Dk_%7B2%7D%5BNOBr_%7B2%7D%5D%5BNO%5D)
=![k_{2} \frac{k_{1}}{k_{-1}}[NO][Br_{2}][NO]](https://tex.z-dn.net/?f=k_%7B2%7D%20%5Cfrac%7Bk_%7B1%7D%7D%7Bk_%7B-1%7D%7D%5BNO%5D%5BBr_%7B2%7D%5D%5BNO%5D)
= ![\frac{k_{1}k_{2}}{k_{-1}}[NO]^{2}[Br_{2}]](https://tex.z-dn.net/?f=%5Cfrac%7Bk_%7B1%7Dk_%7B2%7D%7D%7Bk_%7B-1%7D%7D%5BNO%5D%5E%7B2%7D%5BBr_%7B2%7D%5D)
Thus, rate law of formation of
in terms of reactants is given by
.
Answer: This is true because kinetic energy depends on speed. If there's no speed, then there is no kinetic energy.
The answer would be B) Lower, because pure water freezes at 32 degrees Fahrenheit whereas salt water freezes at 28.4 degrees Fahrenheit. Hopefully this helps!
<span>Heat is the total energy of molecular motion in a substance while temperature is a measure of the average energy of molecular motion in a substance. Heat energy depends on the speed of the particles, the number of particles (the size or mass), and the type of particles in an object.</span>