Answer:
Repeated SN2 reactions occur leading to the formation of a racemic mixture
Explanation:
S-2-iodooctane is a chiral alkyl halide with an asymmetric carbon atom. The presence of an asymmetric carbon atom implies that it can rotate plane polarized light and thus lead to optical isomerism. The two configurations of the compound are R/S according to the Cahn-Prelong-Ingold system.
However, when S-2-iodooctane is treated with sodium iodide in acetone, repeated SN2 reactions occur since the iodide ion is both a good nucleophile and a good leaving group. Hence a racemic modification is formed in the system with time hence we end up with (±)- Iodooctane.
Dmitri Mendeleev
<span> Dmitri Mendeleev and Lothar Meyer individually came up with their own periodic law "when the elements are arranged in order of increasing atomic mass,
certain sets of properties recur periodically.</span>
- E(Bonds broken) = 1371 kJ/mol reaction
- E(Bonds formed) = 1852 kJ/mol reaction
- ΔH = -481 kJ/mol.
- The reaction is exothermic.
<h3>Explanation</h3>
2 H-H + O=O → 2 H-O-H
There are two moles of H-H bonds and one mole of O=O bonds in one mole of reactants. All of them will break in the reaction. That will absorb
- E(Bonds broken) = 2 × 436 + 499 = 1371 kJ/mol reaction.
- ΔH(Breaking bonds) = +1371 kJ/mol
Each mole of the reaction will form two moles of water molecules. Each mole of H₂O molecules have two moles O-H bonds. Two moles of the molecule will have four moles of O-H bonds. Forming all those bond will release
- E(Bonds formed) = 2 × 2 × 463 = 1852 kJ/mol reaction.
- ΔH(Forming bonds) = - 1852 kJ/mol
Heat of the reaction:
is negative. As a result, the reaction is exothermic.
Answer:
0.085 moles of N₂O₅ are needed
Explanation:
Given data:
Mass of NO₂ produces = 7.90 g
Moles of N₂O₅ needed = ?
Solution:
2N₂O₅ → 4NO₂ + O₂
Number of moles of NO₂ produced :
Number of moles = mass/ molar mass
Number of moles = 7.90 g/ 46 g/mol
Number of moles = 0.17 mol
now we will compare the moles of NO₂ with N₂O₅.
NO₂ : N₂O₅
4 : 2
0.17 : 2/4×0.17 = 0.085 mol
Thus, 0.085 moles of N₂O₅ are needed.
