Explanation:
If there are two bond pairs and two lone pairs of electrons the molecular geometry is angular or bent (e.g. H2O). Five electron pairs give a starting point that is a trigonal bipyramidal structure.
Answer:
A small still is separating propane and butane at 135 °C, and initially contains 10 kg moles of a mixture whose composition is x = 0.3 (x = mole fraction butane). Additional mixture (x = 0.3) is fed at the rate of 5 kg mole/hr. The total volume of the liquid in the still is constant, and the concentration of the vapor from the still (xp) is related to x, as follows: Xp = How long will it take for X, to change from 0.3 to 0.35.
Answer:
The equilibrium pressure of NO2 is 0.084 atm
Explanation:
Step 1: Data given
A reaction mixture initially contains 0.86 atm NO and 0.86 atm SO3.
Kp = 0.0118
Step 2: The balanced equation
NO( g) + SO3( g) ⇌ NO2( g) + SO2( g)
Step 3: The initial pressures
p(NO) = 0.86 atm
p(SO3) = 0.86 atm
p(NO2) = 0 atm
p(SO2) = 0 atm
Step 4: The pressure at the equilibrium
For 1 mol NO we need 1 mol SO3 to produce 1 mol NO2 and 1 mol SO2
p(NO) = 0.86 -x atm
p(SO3) = 0.86 -xatm
p(NO2) = x atm
p(SO2) = x atm
Step 5: Define Kp
Kp = ((pNO2)*(pSO2)) / ((pNO)*(pSO3))
Kp = 0.0118 = x²/(0.86 - x)²
X = 0.08427
p(NO) = 0.86 -0.08427 = 0.77573 atm
p(SO3) = 0.86 -0.08427 = 0.77573 atm
p(NO2) = 0.08427 atm
p(SO2) = 0.08427 atm
The equilibrium pressure of NO2 is 0.08427 atm ≈ 0.084 atm
Answer:
The boiling point of sample X and sample Y are exactly the same.
Explanation:
The difference between sample X and sample Y is that they occupy different volumes. However, they both contain pure water. Remember that pure water has uniform composition irrespective of its volume.
Volume does not affect the boiling point as long as the volume is small enough not to give rise to significant pressure changes in the liquid.
The boiling point of a liquid is the temperature at which the pressure exerted by the surroundings upon a liquid is equaled by the pressure exerted by the vapour of the liquid; under this condition, addition of heat results in the transformation of the liquid into its vapour without raising the temperature.
It can be clearly seen from the above that the volume of a solution of pure water does not affect its boiling point hence sample X and sample Y will have the same boiling point.
