Here we have to draw the four isomers of the compound 3-bromo-4-fluorohexane.
The four isomers of the compound is shown in the figure.
In an organic molecule the chiral -C center is that where four (4) different groups are present. In 3-bromo-4-fluorohexane the 3 and 4 positions are chiral centers. The possible isomers of a molecule can be obtained from the formula 2n. As here 2 chiral centers are present thus number of stereoisomers will be 2×2 = 4.
The four different isomers as shown in the figure are 3R-, 4R-; 3S-, 4S; 3R, 4S and 3S-, 4R- 3-bromo-4-fluorohexane.
In the 3-bromo-4-fluorohexane the functional groups are -Br, C₂H₅, -C₃H₆F and -H for 3-position and -F, -C₂H₅, -C₃H₆ and -H for 4-position respectively.
The priority of the -3 position will be Br > C₃H₆F > C₂H₅ > H and for -4 position F > C₃H₆Br > C₂H₅ > H. If the rotation from the higher priority group to lower is clockwise and anticlockwise then the S- and R- notation are used respectively. However if the -H atom is present at the horizontal position then the notation will be reverse.
Thus the four isomers of the compound is shown.
The heat/enthalpy of vaporization of water represents the energy input required to convert one mole of water into vapor at a constant temperature. Intermolecular forces including hydrogen bondings of significant strength hold water molecules in place under its liquid state. Whereas the molecules experience almost no intermolecular interactions under the gaseous state- consider the way noble gases molecules interact. It is thus necessary to supply sufficient energy to overcome all intermolecular interactions present in the substance under its liquid state to convert the substance into a gas. The heat of vaporization is thus related to the strength of the intermolecular interactions.
Water molecules contain hydrogen atoms bonded directly to oxygen atoms. Oxygen atoms are highly electronegative and take major control of electrons in hydrogen-oxygen bonds. Hydrogen atoms in water molecules thus experience a strong partial-positive charge and would attract lone pairs of electron on neighboring water molecules. "Hydrogen bonds" refer to the attraction between hydrogen atoms bonded to electronegative elements and lone pairs of electrons. The hydrogen-oxygen bonds in water molecules are so polarized that hydrogen bonds in water are stronger than both dipole-dipole interactions and London Dispersion Forces in most other molecules. It thus take high amounts of energy to separate water molecules sufficiently apart such that they no longer experience intermolecular interactions and behave collectively like a gas. As a result, water has one of the highest heat of vaporization among covalent molecules of similar sizes.
22.4L
of any gas contains 1 mol of that gas.
50.75g/10L*22.4L/1 mol= 113.68g/mol- this is the mole weight of your gas
1 mol/113.68g*129.3g=1.137403 mol
Set up a ratio
1.137403mol/x L=1 mol/22.4 L
X=25.477827L, or with sig figs, x=25.5L
