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nadezda [96]
3 years ago
6

A critical reaction in the production of energy in biological systems is the hydrolysis of adenosine triphosphate (ATP) to adeno

sine diphosphate (ADP) as described by ATP(aq) + H2O(l)  ADP(aq) + HPO4-2(aq) for which ΔG°rxn = –30.5 kJ/mol at 37.0°C. Calculate the value of ΔGrxn in a biological cell in which [ATP] = 1.2 x10-2 M, [ADP] = 8.4 x10-3 M, and [HPO4-2] = 2.1x10-3 M.
Chemistry
1 answer:
Archy [21]3 years ago
5 0

Answer:

ΔG° of reaction =  -47.3 x 10^{3} J/mol      

Explanation:

As we can see, we have been a particular reaction and Energy values as well.

ΔG° of reaction = -30.5 kJ/mol

Temperature = 37°C.

And we have to calculat the ΔG° of reaction in the biological cell which contains ATP, ADP and HPO4-2:

The first step is to calculate the equilibrium constant for the reaction:

Equilibrium Constant K = \frac{[HPO4-2] x [ADP]}{ATP}

And we have values given for these quantities in the biological cell:

[HP04-2] = 2.1 x 10^{-3} M

[ATP] = 1.2 x 10^{-2} M

[ADP] = 8.4 x 10^{-3} M

Let's plug in these values in the above equation for equilibrium constant:

K = \frac{[2.1x10^{-3}] x [8.4x10^{-3}] }{[1.2 x 10^{-2}] }

K = 1.47 x 10^{-3} M

Now, we have to calculate the ΔG° of reaction for the biological cell:

But first we have to convert the temperature in Kelvin scale.

Temp = 37°C

Temp = 37 + 273

Temp = 310 K

ΔG° of reaction = (-30.5 10^{3}) + (8.314)x (310K)xln(0.00147)

Where 8.314 = value of Gas Constant

ΔG° of reaction = (-30.5 x 10^{3}) + (-16810.68)

ΔG° of reaction = -47.3 x 10^{3} J/mol

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sp2606 [1]

Answer:

54.1 % Ca, 43.2 % O, 2.7% H

Explanation:

Molecular formula for calcium hydroxide is Ca(OH)₂

As we don't have a mass of Ca(OH)₂ to find out the percentage composition, we consider that the question refers to 1 mol of compound.

1 mol of hydroxide weighs 74.08 g

1 mol of hydroxide has 1 mol of Ca, therefore 40.08 g are Ca

2 moles of O therefore 32g are O

2 moles of H therefore 2 g are H

Percentage composition is known as (Mass of element/Total mass) . 100

  • (40.08 / 74.08) . 100 = 54.1 %
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3 years ago
Someone PLEASE help me I don’t remember this.
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Answer: genotype: Ee phenotype: two small eyes.

genotype: RR'  phenotype: pink eyes

genotype: GB phenotype: green and blue splotches

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A 0.56 M solution of AlCl₃ is determined to have a concentration of particles of 1.79 M. What is the van't Hoff factor for AlCl₃
Crank

Answer:

Van't Hoff factor for AlCl₃ = 3 (Approx)

Explanation:

Given:

Number of observed particular = 1.79 M

Number of theoretical particular = 0.56 M

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Van't Hoff factor for AlCl₃

Computation:

Van't Hoff factor for AlCl₃ = Number of observed particular / Number of theoretical particular

Van't Hoff factor for AlCl₃ = 1.79 M / 0.56 M

Van't Hoff factor for AlCl₃ = 3.19

Van't Hoff factor for AlCl₃ = 3 (Approx)

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If 8cm^3 of H2 reacts with an excess of Cl2, calculate how much of the HCL(g) is produced.
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First, we need the balanced equation: H₂ + Cl₂ ---> 2HCl

since not much information is given, I am assuming we are at STP and that 22.4 Liters= 1 mol

1) let's convert the volume to moles using the molar volume of a gas. also we need to convert the cm₃ to mL, then to Liters.

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7.1x10⁻⁴ mol HCl (36.51 g/mol)=<span> 0.026 grams HCl</span>
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