Answer:
Explanation:
(a) Part 1: 
reaction. This is a nucleophilic substitution reaction in which we have two steps. Firstly, chlorine, a good leaving group, leaves the carbon skeleton to form a relatively stable secondary carbocation. This carbocation is then attacked by the hydroxide anion, our nucleophile, to form the final product.
To summarize, this mechanism takes places in two separate steps. The mechanism is attached below.
Part 2: 
reaction. This is a nucleophilic substitution reaction in which we have one step. Our nucleophile, hydroxide, attacks the carbon and then chlorine leaves simultaneously without an intermediate carbocation being formed.
The mechanism is attached as well.
(b) The rate determining step is the slow step. Formation of the carbocation has the greatest activation energy, so this is our rate determining step for . For , we only have one step, so the rate determining step is the attack of the nucleophile and the loss of the leaving group.
Answer:
Explanation:
To solve this problem, we must understand the relationship between mass of a substance and the number of atoms.
Atoms are the smallest indivisible particles of any matter. A substance can be made up of several number of atoms in their space.
The mass of any substance is a function of the amount of atoms its contains.
The mass of a substance is related in chemistry to the amount of atoms its contains using the parameter called the number of moles.
A mole is the amount of substance that contains the Avogadro's number of particles. This number is 6.02 x 10²³ particles. The particles here can be protons, neutrons, electrons, atoms e.t.c.
Now,
Number of moles = 
Molar mass of copper = 63.6g/mole
Number of moles = 
= 0.03mole
Since 1 mole of a substance contains 6.02 x 10²³atoms
0.03 mole of copper will contain 0.03 x 6.02 x 10²³atoms
= 1.89 x 10²² atoms
He needs to add 1.89 x 10²² atoms to make 2g of the sample.
Here is an acid-base reaction. Hydrochloric acid (HCl) reacts with strontium hydroxide [ Sr(OH)2 ]
Ions H+ and OH- neutralize each other. If the amounts are not equal, one of them will be in excess.
Follow the steps as
1. Find moles of ions: mole= Molarity * Volume (in liter) ; n= M * V OR millimole = Molarity * Volume (in ml) ;
2. Write the equation
3. Find out excess ion
4. Use final volume (V acid + V base ) to calculate concentration of excess ion.
n HCI = 28 ml * 0.10 M = 0.28 mmol, releases 0.28 mmol H+ ions
n Sr(OH)2= 60 ml * 0.10 M= 0.60 mmol, releases 2* 0.60=1.20 mmol OH- ions
since Sr(OH)2⇒ Sr2+ + 2OH-
Neutralization reaction is OH- + H+ ---> H2O. The ratio is 1:1. That means 1 mmol hydroxide ions will neutralize 1 mmol hydrogen ions. Since OH- ions are greater in amount, they will be in excess
n(OH-) - n(H+)= 1.20 - 0.28 = 0.92 mmol OH- ions UNREACTED.
Total volume= V acid + V base= 28 ml + 60 ml = 98 ml
Molarity of OH- ions= mole / Vtotal = 0.92/98= 0.009 M
The answer is 0.009 M.
The soulustion. turn cloudy due to the precipitation of Sulphur.
The molecular formula of sucrose is - C₁₂H₂₂O₁₁
molecular mass of sucrose - 342 g/mol
molarity of sucrose solution is 0.758 M
In 1 L solution the number of sucrose moles are - 0.758 mol
Therefore in 1.55 L solution, sucrose moles are - 0.758 mol/L x 1.55 L
= 1.17 mol
The mass of 1.17 mol of sucrose is - 1.17 mol x 342 g/mol = 4.00 x 10² g
