Liquids are similar to gases in that they both have

Which of the solutions have greatest osmotic pressure 30% sucrose 60% sucrose or 30% magnesium sulfate?

zaharov [31]

Osmotic pressure is the minimum amount of pressure a solution must exert in order to prevent from crossing a barrier by osmosis. Solute molecules have difficulty crossing semipermeable membranes, so the more solutes that are in a solution, the higher the osmotic pressure will be. Between 30% sucrose and 60% sucrose, 60% sucrose will have a greater osmotic pressure than 30% because it has a higher percentage of solutes. However, since sucrose has a higher potential to cross semipermeable membranes and is more absorbable than magnesium sulfate, magnesium sulfate would have a higher osmotic pressure than 60% sucrose even though 60% sucrose has higher molecules.

4 0

3 years ago

From the value Kf=1.2×109 for Ni(NH3)62+, calculate the concentration of NH3 required to just dissolve 0.016 mol of NiC2O4 (Ksp

Nina [5.8K]

Answer: The concentration of $NH_3$ required will be 0.285 M.

Explanation:

To calculate the molarity of $NiC_2O_4$ , we use the equation:

$\text{Molarity of the solution}=\frac{\text{Moles of solute}}{\text{Volume of solution (in L)}}$

Moles of $NiC_2O_4$ = 0.016 moles

Volume of solution = 1 L

Putting values in above equation, we get:

$\text{Molarity of }NiC_2O_4=\frac{0.016mol}{1L}=0.016M$

For the given chemical equations:

$NiC_2O_4(s)\rightleftharpoons Ni^{2+}(aq.)+C_2O_4^{2-}(aq.);K_{sp}=4.0\times 10^{-10}$

$Ni^{2+}(aq.)+6NH_3(aq.)\rightleftharpoons [Ni(NH_3)_6]^{2+}+C_2O_4^{2-}(aq.);K_f=1.2\times 10^9$

Net equation: $NiC_2O_4(s)+6NH_3(aq.)\rightleftharpoons [Ni(NH_3)_6]^{2+}+C_2O_4^{2-}(aq.);K=?$

To calculate the equilibrium constant, K for above equation, we get:

$K=K_{sp}\times K_f\\K=(4.0\times 10^{-10})\times (1.2\times 10^9)=0.48$

The expression for equilibrium constant of above equation is:

$K=\frac{[C_2O_4^{2-}][[Ni(NH_3)_6]^{2+}]}{[NiC_2O_4][NH_3]^6}$

As, $NiC_2O_4$ is a solid, so its activity is taken as 1 and so for $C_2O_4^{2-}$

We are given:

$[[Ni(NH_3)_6]^{2+}]=0.016M$

Putting values in above equations, we get:

$0.48=\frac{0.016}{[NH_3]^6}}$

$[NH_3]=0.285M$

Hence, the concentration of $NH_3$ required will be 0.285 M.

7 0

3 years ago

Carbon has an atomic number of 6, but the following orbital notation for carbon is incorrect. Explain the error in terms of the

a_sh-v [17]

Carbon:

1s is filled. 2s is filled. 2p is shown to contain two electrons in one orbital and no electrons in the other two orbitals.

8 0

3 years ago

Calculate the cfse for a d^3 system in an octahedral field in units of ∆_o. In other words, do not enter "∆_o" with your answer.

Rudik [331]

Magnetic moment (spin only) of octahedral complex having CFSE=−0.8Δo and surrounded by weak field ligands can be : Q

To answer this, the Crystal Field Stabilization Energy has to be calculated for a (d3 metal in both configurations. The geometry with the greater stabilization will be the preferred geometry. So for tetrahedral d3, the Crystal Field Stabilization Energy is: CFSE = -0.8 x 4/9 Δo = -0.355 Δo.

[Co(CN)64-] is also an octahedral d7 complex but it contains CN-, a strong field ligand. Its orbital occupancy is (t2g)6(eg)1 and it therefore has one unpaired electron. In this case the CFSE is −(6)(25)ΔO+(1)(35)ΔO+P=−95ΔO+P.

The crystal field stabilization energy (CFSE) (in kJ/mol) for complex, [Ti(H2O)6]3+. According to CFT, the first absorption maximum is obtained at 20,3000cm−1 for the transition.

To learn more about crystal field stabilization energy visit:brainly.com/question/29389010

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8 0

1 year ago

How many liters are in .0025 millililiters

jekas [21]

Answer: 0.0000025 liters

8 0

2 years ago